Sigloite

Fe3+Al2(PO4)2(OH)3 · 7H2O
IMA status
  • Approved
IMA symbol
Sig
Discovered
1962
Also known as
  • Hydrated Paravauxite
  • Hydroparavauxite
  • Sigloiet

Where it forms, where it's found

Type locality
Siglo Veinte Mine
  1. Llallagua
  2. Rafael Bustillo Province
  3. Potosí
  4. Bolivia

-18.4229°, -66.5925°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Light brown · straw-yellow · pale brownish orange
Cleavage
Perfect

On (010), perfect; on (001), good

Density
2.35 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 76° · 2V calc = 82°
Refractive index
1.563 – 1.619
Surface relief
Moderate
Principal indices
nα 1.563 · nβ 1.586 · nγ 1.619
Dispersion
strong
Extinction
X (90°,32°); Y (–144°,70°); Z (–46°,66°) [using (φ,ρ)]
Michel-Lévy diagramhighlighted lineδ = 0.0560
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]560 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation560 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.190(2) Å · b = 10.419(4) Å · c = 7.033(3) Å
Cell angles
α = 105.00(3) ° · β = 111.31(3) ° · γ = 6970.87(3) °
Ratio a:b:c
1 : 2.008 : 1.355
Z
1
Morphology

Forms include (001), (010), (100), (110), (110), (120), (011), (111), (112).

Type-locality form

Cavities filled with straw yellow intergrowths of crystals and crystals perched on wavellite overgrowths on quartz.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
60.39%
15PPhosphorusPhosphorus230.97461.948
12.99%
26FeIronIron155.84555.845
11.71%
13AlAluminiumAluminium226.98253.964
11.32%
1HHydrogenHydrogen171.00817.136
3.59%
Total476.875100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hydrated Paravauxite
  • Hydroparavauxite
  • Sigloiet

In other languages

German
Sigloit
Italian
Sigloite

Classification

Strunz
10th ed.

8.DC.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.30SigloiteSpecies
Dana
8th ed.

42.11.14.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.14Vauxite GroupGroup
  • 42.11.14.03SigloiteSpecies
CIM

19.14.26

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.26SigloiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1962Hurlbut, Cornelius S., Honea, Russell (1962) Sigloite, a new mineral from Llallagua, Bolivia. American Mineralogist, 47 (1-2) 1-8
  2. 1988Hawthorne, F.C. (1988) Sigloite: the oxidation mechanism in [M23+(PO4)2(OH)2(H2O)2]2- structures. Mineralogy and Petrology, 38, 201-211.
  3. 1989Jambor, John L., Burke, Ernst A. J. (1989) New Mineral Names. American Mineralogist, 74 (11-12) 1399-1404
  4. 2005(2005) Sigloite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2013Frost, Ray L., Xi, Yunfei, Scholz, Ricardo, Belotti, Fernanda Maria, Filho, Mauro Cândido (2013) The phosphate mineral sigloite Fe3+Al2(PO4)2(OH)3·7(H2O), an exception to the paragenesis rule – A vibrational spectroscopic study. Journal of Molecular Structure, 1033. 258-264 doi:10.1016/j.molstruc.2012.10.020DOI: 10.1016/j.molstruc.2012.10.020
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sigloite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sigloite-3657},
  note      = {Accessed 2026-05-11}
}