Stewartite

Mn2+Fe3+2(PO4)2(OH)2 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Stw
Discovered
1912
Also known as
  • Stewartiet
  • Stewartite (of Schaller)

Where it forms, where it's found

Geological setting

In pegmatite, as an alteration product of lithiophilite which it replaces along cleavage cracks.

Type locality
Stewart Mine
  1. Tourmaline Queen Mountain (Pala Mtn
  2. Queen Mtn)
  3. Pala
  4. Pala Mining District
  5. San Diego County
  6. California
  7. USA

33.3811°, -117.0625°

47recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent · Translucent
Colour
Yellow to brownish yellow
Streak
White
Tenacity
very brittle
Cleavage
None Observed
Density
2.94 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.612 – 1.681
Surface relief
Moderate
Principal indices
nα 1.612 – 1.630 · nβ 1.653 – 1.658 · nγ 1.660 – 1.681
Birefringence
0.050
Pleochroism
Visible

X = Colourless Y = Light yellow Z = Yellow

Dispersion
r < v strong
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]500 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation500 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 10.398 Å · b = 10.672 Å · c = 7.223 Å
Cell angles
α = 90.10 ° · β = 109.10 ° · γ = 71.83 °
Ratio a:b:c
1 : 1.026 : 0.695
Z
2
Morphology

Crystals minute; tufts of fibers.

Twinning

Twins showing small "fish-tail" re-entry angles (010)

Type-locality form

Fine fibers arranged normal to the cleavage cracks of the lithiophilite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
53.86%
26FeIronIron255.845111.690
20.89%
15PPhosphorusPhosphorus230.97461.948
11.59%
25MnManganeseManganese154.93854.938
10.27%
1HHydrogenHydrogen181.00818.144
3.39%
Total534.702100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Stewartiet
  • Stewartite (of Schaller)

In other languages

German
Stewartit
Spanish
Stewartita
Italian
Stewartite

Classification

Strunz
10th ed.

8.DC.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.30StewartiteSpecies
Dana
8th ed.

42.11.10.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.10Laueite GroupGroup
  • 42.11.10.02StewartiteSpecies
CIM

19.12.27

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.27StewartiteSpecies

Group, growth & confusion

Commonly confused with
4 minerals

Literature, links & citation

Citations
  1. 1910Lacroix, A. (1910) Minéralogie de la France et de ses colonies Vol. 4. Library Polytechnique, Paris.
  2. 1912Schaller, W.T. (1912) New manganese phosphates from the gem tourmaline field of Southern California. Journal of the Washington Academy of Sciences: 2: 143-145.
  3. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  4. 1974Moore, Paul Brian, Araki, Takaharu (1974) Stewartite, Mn2+Fe3+2(OH)2(H2O)6[PO4]2·2H2O: Its atomic arrangement. American Mineralogist, 59 (11-12) 1272-1276
  5. 1975Moore, P.B. (1975): Laueite, pseudolaueite, stewartite and metavauxite; a study in combinatorial polymorphism. Neues Jahrbuch für Mineralogie, Abhandlungen: 123: 148-159.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Stewartite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/stewartite-3772},
  note      = {Accessed 2026-05-11}
}