Wagnerite

Mg2(PO4)F
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wag
Discovered
1821
Also known as
  • Crifiolite
  • Cryphiolite
  • Kjerulfine
  • +5 more

Where it forms, where it's found

Type locality
Höllgraben
  1. Werfen
  2. St. Johann im Pongau District
  3. Salzburg
  4. Austria

47.4507°, 13.1891°

59recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellow · brown · red brown · light grey · green · red · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

On (100) and (120), imperfect; on (001), in traces.

Fracture
Conchoidal · Sub-Conchoidal
Density
3.15 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 25 – 35°
Refractive index
1.5678 – 1.5824
Surface relief
Moderate
Principal indices
nα 1.5678 · nβ 1.5719 · nγ 1.5824
Birefringence
0.046
Pleochroism
Non-pleochroic
Dispersion
r > v weak
Extinction
Y = b; Z ∧ c = 21°.
UV response
Not fluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0460
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]460 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation460 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 11.94(1) Å · b = 12.71(1) Å · c = 9.65(1) Å
Cell angles
β = 108.2 °
Ratio a:b:c
1 : 1.064 : 0.808
Z
16
Morphology

Crystals prismatic [001] with the prismatic faces vertically striated or vicinally rounded. Crystals large and coarse at times. Rarely tabular (100). Massive.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
39.36%
12MgMagnesiumMagnesium224.30548.610
29.90%
15PPhosphorusPhosphorus130.97430.974
19.05%
9FFluorineFluorine118.99818.998
11.69%
Total162.578100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Crifiolite
  • Cryphiolite
  • Kjerulfine
  • Kryphiolith
  • Magnésie phosphatée
  • Phosphorsaurer Talk
  • Pleuroclase
  • Pleuroklas

In other languages

German
Wagnerit
Spanish
wagnerita
Italian
Wagnerite
Portuguese
Wagnerite
Chinese
氟磷镁石

Classification

Strunz
10th ed.

8.BB.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.15WagneriteSpecies
Dana
8th ed.

41.06.02.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.02Wagnerite GroupGroup
  • 41.06.02.01WagneriteSpecies
CIM

22.1.22

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.1Phosphates, arsenates or vanadates with fluorideGroup
  • 22.1.22WagneriteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
6 minerals

Literature, links & citation

Citations
  1. 1821Fuchs, J.N. (1821) Ueber den wagnerit. Journal für Chemie und Physik: 33: 269-277. (as Phosphorsaurer Talk and as Wagnerit).
  2. 1823Breithaupt, August (1823) Vollständige Charakteristik des Mineral-Systems (1st ed.). Arnoldischen Buchhandlung.
  3. 1852Brooke, Henry J., Phillips, William (1852) An Elementary Introduction to Mineralogy (6th ed.)
  4. 1873Kobell, F. (1873) Ueber den Kjerulfin, eine neue Mineralspecies von Bamle in Norwegen. Journal für praktische Chemie: 7: 272.
  5. 1879Brögger (1879) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 3: 476.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wagnerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wagnerite-4229},
  note      = {Accessed 2026-05-11}
}