Zwieselite

Fe2+2(PO4)F
IMA status
  • Approved
  • Grandfathered
IMA symbol
Zwi
Discovered
1841
Also known as
  • Zwieseliet
  • Zwiselite

Where it forms, where it's found

Geological setting

Granite pegmatite.

Type locality
Birkhöhe Quarry (Birkenhöhe Quarry)
  1. Zwiesel
  2. Regen District
  3. Lower Bavaria
  4. Bavaria
  5. Germany

49.0131°, 13.2342°

48recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Resinous
Transparency
Translucent
Colour
Dark brown · black (altered)
Streak
White to tan
Tenacity
brittle
Cleavage
Distinct/Good

(001) good, (010) fair, (100) poor.

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.89 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 58° · 2V calc = 60°
Refractive index
1.686 – 1.713
Surface relief
High
Principal indices
nα 1.686 – 1.696 · nβ 1.690 – 1.704 · nγ 1.703 – 1.713
Birefringence
0.017
Pleochroism
Visible

Yellow brown to reddish brown.

Dispersion
r > v
UV response
Not fluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 12.085 Å · b = 6.536 Å · c = 9.910 Å
Cell angles
β = 105.63 °
Ratio a:b:c
1 : 0.541 : 0.820
Z
8
Morphology

Usually massive, morphological crystals unknown.

Comment

I2/a

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron255.845111.690
49.49%
8OOxygenOxygen415.99963.996
28.36%
15PPhosphorusPhosphorus130.97430.974
13.73%
9FFluorineFluorine118.99818.998
8.42%
Total225.658100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg
  • Ca

Synonyms

  • Zwieseliet
  • Zwiselite

In other languages

French
zwiesélite
German
Zwieselit
Italian
zwieselite

Classification

Strunz
10th ed.

8.BB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.10ZwieseliteSpecies
Dana
8th ed.

41.06.01.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.01Zwieselite GroupGroup
  • 41.06.01.01ZwieseliteSpecies
CIM

22.1.25

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.1Phosphates, arsenates or vanadates with fluorideGroup
  • 22.1.25ZwieseliteSpecies

Group, growth & confusion

In the same group
3 members
Commonly confused with
5 minerals

Literature, links & citation

Citations
  1. 1841Breithaupt, J.F.A. (1841) Phyletites ferrosus oder Zwiselit. Vollständige Handbuch der Mineralogie. Vol. 2: 299-300. (as zwiselit)
  2. 1841Breithaupt, J.F.A. (1841) Phyletites ferrosus oder Zwiselit. Vollständige Handbuch der Mineralogie. Vol. 2: 299-300.
  3. 1847Glocker, Ernst Friedrich (1847) Generum et specierum mineralium, secundum ordines naturales digestorum synopsis, omnium, quotquot adhuc reperta sunt, mineralium nomina complectens [A synopsis of the genera and species of minerals, according to their natural orders, including the names of all the minerals that have yet been discovered.]. Eduardus Anton. 348 pp.
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1957Fisher, D. Jerome (1957) Isokite and triplite from Bohemia. Mineralogical Magazine and Journal of the Mineralogical Society, 31 (238). 587-602 doi:10.1180/minmag.1957.031.238.05DOI: 10.1180/minmag.1957.031.238.05
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zwieselite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zwieselite-4436},
  note      = {Accessed 2026-05-11}
}