Wolfeite

Fe2+2(PO4)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wol
Discovered
1949
Also known as
  • Wolfeiet

Where it forms, where it's found

Geological setting

Granitic pegmatite.

Granitic pegmatites.

Type locality
Palermo No. 1 Mine
  1. Groton
  2. Grafton County
  3. New Hampshire
  4. USA

43.7513°, -71.8896°

47recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Red-brown to dark brown · green (rare) · light brown in transmitted light.
Streak
White, off-white.
Tenacity
brittle
Cleavage
Distinct/Good

On (010), good; on (120), fair; on (110), very poor.

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.79 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 51°
Refractive index
1.741 – 1.759
Surface relief
High
Principal indices
nα 1.741 – 1.750 · nβ 1.742 – 1.750 · nγ 1.746 – 1.759
Birefringence
0.005
Pleochroism
Weak

Faintly pleochroic in thick grains.

Dispersion
strong
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0050
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]50 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation50 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 12.20 Å · b = 13.17 Å · c = 9.79 Å
Cell angles
β = 108 °
Ratio a:b:c
1 : 1.080 : 0.802
Z
16
Morphology

Almost always massive, rare crystals prismatic [001], with the prism zone striated vertically.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron255.845111.690
49.94%
8OOxygenOxygen515.99979.995
35.76%
15PPhosphorusPhosphorus130.97430.974
13.85%
1HHydrogenHydrogen11.0081.008
0.45%
Total223.667100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Wolfeiet

In other languages

German
Wolfeit
Italian
Wolfeite

Classification

Strunz
10th ed.

8.BB.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.15WolfeiteSpecies
Dana
8th ed.

41.06.03.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.03Wolfeite GroupGroup
  • 41.06.03.01WolfeiteSpecies
CIM

19.12.12

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.12WolfeiteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
5 minerals
Commonly confused with
5 minerals

Literature, links & citation

Citations
  1. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  2. 1900Kovář, F., Slavík, F. (1900) Ueber Triplit von Wien und Cyrillof in Mahren und seine Zersetzungspoducte. Verhandlungen der KK Geologischen Reichsanstalt Wien: 50: 347-404.
  3. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  4. 1924Müllbauer, F. (1924) Die Phosphatpegmatite von Hagendorf i. Bayern. (Neue Beobachtungen.) [The phosphate pegmatite of Hagendorf, Bavaria. (New observations.)]. Zeitschrift für Kristallographie, Kristallgeometrie, Kristallphysik, Kristallchemie, 61 (1). 318-336 doi:10.1524/zkri.1924.61.1.318DOI: 10.1524/zkri.1924.61.1.318
  5. 1938Hägele, G. (1938) Sarkinit und Triploidit. Zentralblatt für Mineralogie, Geologie und Paläontologie. Abt. A: 267-273.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wolfeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wolfeite-4304},
  note      = {Accessed 2026-05-11}
}