Triplite

Mn2+2(PO4)F
IMA status
  • Approved
  • Grandfathered
IMA symbol
Trl
Discovered
1813
Also known as
  • Eisenapatit
  • Eisenpecherz (of Werner)
  • Manganèse phosphaté
  • +6 more

Where it forms, where it's found

Geological setting

Granitic pegmatites of the complex, phosphate-rich type. Also occurs in high-temperature veins (Nevada).

Type locality
Chanteloube
  1. Razès
  2. Bellac
  3. Haute-Vienne
  4. Nouvelle-Aquitaine
  5. France

46.0568°, 1.3608°

210recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Brown · red-brown · dark brown · black (altered) · light brownish-yellow to dark reddish brown in transmitted light.
Streak
White to brown
Tenacity
brittle
Cleavage
Distinct/Good

On (001), good; on (010), fair; and on (100), poor.

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
3.5 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70 – 90° · 2V calc = 72°
Refractive index
1.65 – 1.6905
Surface relief
High
Principal indices
nα 1.65 – 1.6695 · nβ 1.66 – 1.6737 · nγ 1.68 – 1.6905
Birefringence
0.03
Pleochroism
Visible

Usually distinct in shades of yellow-brown or reddish brown.

Dispersion
relatively strong
UV response
Not fluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 11.97 Å · b = 6.52 Å · c = 10.09 Å
Cell angles
β = 105.62 °
Ratio a:b:c
1 : 0.545 : 0.843
Z
8
Morphology

Crystals are rare, commonly crude, and incompletely developed. Usually massive.

Comment

Non-standard space group I2/a.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese254.938109.876
49.08%
8OOxygenOxygen415.99963.996
28.59%
15PPhosphorusPhosphorus130.97430.974
13.84%
9FFluorineFluorine118.99818.998
8.49%
Total223.844100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sc

Synonyms

  • Eisenapatit
  • Eisenpecherz (of Werner)
  • Manganèse phosphaté
  • Manganèse phosphaté ferrifère
  • Phosphate natif de fer melangé de manganèse
  • Phosphate of Iron and Manganese
  • Phosphormangan
  • Retinbaryte
  • Tripliet

In other languages

French
Triplite
German
Triplit
Spanish
Triplita
Italian
Triplite
Japanese
トリプル石
Russian
триплит
Arabic
تريبلايت · تريبليت

Classification

Strunz
10th ed.

8.BB.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.10TripliteSpecies
Dana
8th ed.

41.06.01.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.01Zwieselite GroupGroup
  • 41.06.01.02TripliteSpecies
CIM

22.1.23

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.1Phosphates, arsenates or vanadates with fluorideGroup
  • 22.1.23TripliteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
7 minerals
Commonly confused with
5 minerals

Literature, links & citation

Citations
  1. 1802Vauquelin (1802) Journal des mines {superseded by Annales des mines}: 11: 295 (as Phosphate natif de fer melangé de manganèse).
  2. 1802Vauquelin (1802) Annales de chimie, Paris: 41: 242m (as Phosphate natif de fer melangé de manganèse).
  3. 1806Lucas, J.A.H. (1806) Tableau métodique des espèces minéraux. Part 1: 169 (as Manganèse phosphaté).
  4. 1808Werner (1808) (as Eisenpecherz).
  5. 1809Haüy, René Just (1809) Tableau comparatif des résultats de la Cristallographie et de l'analyse Chimique, relativement a la Classification des Minéraux.. Chez Courcier, Paris.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Triplite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/triplite-4021},
  note      = {Accessed 2026-05-11}
}