Walthierite

Ba0.5Al3(SO4)2(OH)6
IMA status
  • Approved
IMA symbol
Wtr
Discovered
1991
IMA approved
1991
Also known as
  • IMA1991-008
  • Walthieriet

Where it forms, where it's found

Type locality
Retna vein
  1. Tambo Mine
  2. Vicuña
  3. Elqui Province
  4. Coquimbo
  5. Chile
4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
White · light yellow
Streak
white
Cleavage
Perfect

(001)

Density
3.02 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.588 – 1.604
Surface relief
Moderate
Principal indices
nω 1.588 · nε 1.604
Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Cell parameters
a = 6.992(4) Å · c = 34.443(8) Å
Z
6
Comment

Point Group: _3 2/m or 3m.; Space Group: [R_3m or R3m] (by analogy to alunite)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
50.48%
13AlAluminiumAluminium326.98280.946
18.24%
56BaBariumBarium0.5137.32768.663
15.47%
16SSulfurSulfur232.06064.120
14.45%
1HHydrogenHydrogen61.0086.048
1.36%
Total443.764100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1991-008
  • Walthieriet

In other languages

German
IMA 1991-008 · Walthierit
Italian
Walthierite
Chinese
沃尔希尔石

Classification

Strunz
10th ed.

7.BC.10

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.10WalthieriteSpecies
Dana
8th ed.

30.02.04.07

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.04Alunite Group (Alunite Subgroup)Group
  • 30.02.04.07WalthieriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1992Li, Gejing; Peacor, Donald R.; Essene, Eric J.; Brosnahan, David R.; Beane, Richard E. (1992) Walthierite, Ba0.5[]0.5Al3(SO4)2(OH)6,and huangite, Ca0.5[]0.5Al3(SO4)2(OH)6, two new minerals of the alunite group from the Coquimbo region, Chile. American Mineralogist, 77 (11-12). p.1275-1284.
  2. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  3. 1999Jambor, John L. (1999) Nomenclature of the alunite supergroup. The Canadian Mineralogist, 37 (6). 1323-1341
  4. 2005(2005) Walthierite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2010Bayliss, P., Kolitsch, U., Nickel, E. H., Pring, A. (2010) Alunite supergroup: recommended nomenclature. Mineralogical Magazine, 74 (5) 919-927 doi:10.1180/minmag.2010.074.5.919 DOI: 10.1180/minmag.2010.074.5.919
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Walthierite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/walthierite-4240},
  note      = {Accessed 2026-05-11}
}