Whewellite

Ca(C2O4) · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Whe
Discovered
1852
Also known as
  • Kohlenspath
  • Oxacalcite
  • Oxalate of Lime
  • +5 more

Where it forms, where it's found

Geological setting

In carbonate-sulphide veins, geodes, or septarian nodules; associated with coal measures or in surrounding rock containing organic matter; in some uranium deposits.

69recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
White · yellow · brown · colourless · colourless in transmitted light.
Tenacity
brittle
Cleavage
Very Good

On (101) very good; on (010), imperfect; on (001), (110), indistinct.

Fracture
Conchoidal
Density
2.21 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 80 – 84° · 2V calc = 84°
Refractive index
1.489 – 1.65
Surface relief
Moderate
Principal indices
nα 1.489 – 1.491 · nβ 1.553 – 1.554 · nγ 1.649 – 1.650
Dispersion
none
Extinction
X = b; Z ∧ c = 30°.
Michel-Lévy diagramhighlighted lineδ = 0.1595
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1595 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1595 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 6.290 Å · b = 14.583 Å · c = 10.116 Å
Cell angles
β = 109.46 °
Ratio a:b:c
1 : 2.318 : 1.608
Z
2
Morphology

Crystals equant to short prismatic [001], typically distorted with faces commonly irregularly developed, exhibiting forms (001), (011), (010), (110), (120), (132), (101), plus several additional. Cleavable massive.

Twinning

Very common on (101) as twin and contact plane, with or without reentrant angles, yielding heart-shaped or prismatic, and of pseudo-orthorhombic appearance.

Type-locality form

Crystals to 0.1 to 0.25 inches wide on calcite matrix. Locality unknown.

Comment

Other (standard) setting in space group: P21/n, with 6.29, 14.58, 9.97 Å, 107°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
54.75%
20CaCalciumCalcium140.07840.078
27.43%
6CCarbonCarbon212.01124.022
16.44%
1HHydrogenHydrogen21.0082.016
1.38%
Total146.111100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Kohlenspath
  • Oxacalcite
  • Oxalate of Lime
  • Thierschite
  • Tierschit
  • Vevellit
  • Vevellita
  • Vevellite

In other languages

French
Whewellite
German
Whewellit
Spanish
Whewellita
Italian
Whewellite
Japanese
蓚酸石灰石
Chinese
水草酸鈣石 · 草酸钙石
Simplified Chinese
草酸钙石
Traditional Chinese
水草酸鈣石

Classification

Strunz
10th ed.

10.AB.45

  • 10Organic CompoundsClass
  • 10.ASalts of organic acidsDivision
  • 10.ABOxalatesGroup
  • 10.AB.45WhewelliteSpecies
Dana
8th ed.

50.01.01.01

  • 50Organic CompoundsClass
  • 50.01OxalatesType
  • 50.01.01— unnamed intermediate level —Group
  • 50.01.01.01WhewelliteSpecies
CIM

31.1.5

  • 31Oxalates, Citrates, Mellitates and AcetatesClass
  • 31.1OxalatesGroup
  • 31.1.5WhewelliteSpecies

Group, growth & confusion

Often grow together
5 minerals

Literature, links & citation

Citations
  1. 1840Brooke, H.J. (1840) On crystallized native oxalate of lime. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science: 16(105): 449–450.
  2. 1844Shepard, C.U. (1844) Treatise on Mineralogy. second edition: 111 (as Oxacalcite).
  3. 1852Brooke, Henry J., Phillips, William (1852) An Elementary Introduction to Mineralogy (6th ed.)
  4. 1853Liebig (1853) Annalen der Chemie, Leipzig (Justus Liebig’s): 86: 113 (as Thierschite).
  5. 1854Dana, James D. (1854) A System of Mineralogy (4th ed.). p.1-849.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Whewellite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/whewellite-4276},
  note      = {Accessed 2026-05-11}
}