Whiteite-(CaFeMg)

CaFe2+Mg2Al2(PO4)4(OH)2 · 8H2O
IMA status
  • Approved
IMA symbol
Wt-CaFeMg
IMA approved
1975
Also known as
  • IMA1975-001
  • Whiteiet-(CaFeMg)

Where it forms, where it's found

Geological setting

Granite pegmatite

Type locality
Ilha claim
  1. Taquaral
  2. Itinga
  3. Minas Gerais
  4. Brazil

-16.6453°, -41.8637°

11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pink-brown · light brown
Cleavage
Perfect

Good to perfect, (001)

Density
2.58 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 40 – 50° · 2V calc = 88°
Refractive index
1.58 – 1.59
Surface relief
Moderate
Principal indices
nα 1.58 · nβ 1.585 · nγ 1.59
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 14.87(2) Å · b = 6.95(3) Å · c = 10.13 Å
Cell angles
β = 112.8(3) °
Ratio a:b:c
1 : 0.467 : 0.681
Z
2
Morphology

Warped crystals showing the forms c(001)and n(111).

Twinning

Twinned by reflection on (001), imparting a pseudo-orthorhombic appearance to the composite.

Type-locality form

Pale tan to brown bunched aggregates of small (1-5 mm) tabular crystals to large (up to 2 cm) thick tabular canoe-shaped individuals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
54.99%
15PPhosphorusPhosphorus430.974123.896
16.38%
26FeIronIron155.84555.845
7.38%
13AlAluminiumAluminium226.98253.964
7.13%
12MgMagnesiumMagnesium224.30548.610
6.42%
20CaCalciumCalcium140.07840.078
5.30%
1HHydrogenHydrogen181.00818.144
2.40%
Total756.511100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1975-001
  • Whiteiet-(CaFeMg)

In other languages

German
IMA 1975-001 · Whiteit-(CaFeMg)
Italian
IMA1975-001 · Whiteite- · whiteite-(CaFeMg)
Chinese
磷铝镁铁钙石

Classification

Strunz
10th ed.

8.DH.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.15Whiteite-(CaFeMg)Species
Dana
8th ed.

42.11.03.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.03Whiteite GroupGroup
  • 42.11.03.01Whiteite-(CaFeMg)Species
CIM

19.12.60

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.60Whiteite-(CaFeMg)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 1978Moore, Paul Brian, Ito, Jun (1978) I. Whiteite, a new species, and a proposed nomenclature for the jahnsite-whiteite complex series. II. New data on xanthoxenite. III. Salmonsite discredited. Mineralogical Magazine, 42 (323) 309-323 doi:10.1180/minmag.1978.042.323.01 DOI: 10.1180/minmag.1978.042.323.01
  2. 1979Fleischer, Michael, Chao, George Y., Pabst, and Adolf (1979) New Mineral Names. American Mineralogist, 64 (3-4) 464-467
  3. 2005(2005) Whiteite-(CaFeMg). Handbook of Mineralogy. Mineralogical Society of America
  4. 2011Capitelli, Francesco, Chita, Giuseppe, Cavallo, Andrea, Bellatreccia, Fabio, Della Ventura, Giancarlo (2011) Crystal structure of whiteite-(CaFeMg) from Crosscut Creek, Canada. Zeitschrift für Kristallographie - Crystalline Materials, 226 (9) 731-738 doi:10.1524/zkri.2011.1393DOI: 10.1524/zkri.2011.1393
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Whiteite-(CaFeMg) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/whiteite-cafemg-4277},
  note      = {Accessed 2026-05-11}
}