Whiteite-(CaMnMn)

CaMn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O
IMA status
  • Approved
IMA symbol
Wt-CaMnMn
IMA approved
2011
Also known as
  • IMA2011-002
  • Whiteiet-(CaMnMn)

Where it forms, where it's found

Geological setting

Granitic pegmatite.

Type locality
Hagendorf South Pegmatite
  1. Hagendorf
  2. Waidhaus
  3. Neustadt an der Waldnaab District
  4. Upper Palatinate
  5. Bavaria
  6. Germany

49.6503°, 12.4597°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless to pale yellow

Color depending on Al–Fe3+ substitution

Streak
White
Tenacity
brittle
Cleavage
Perfect

on (001)

Fracture
Step-Like
Density
2.70 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60° · 2V calc = 60.3°
Refractive index
1.589 – 1.601
Surface relief
Moderate
Principal indices
nα 1.589 · nβ 1.592 · nγ 1.601
Dispersion
Not observed
Extinction
X = b, Z ∧ a = 5º.
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P2/a
Cell parameters
a = 15.02(2) Å · b = 6.95(1) Å · c = 10.13(3) Å
Cell angles
β = 111.6(1) °
Ratio a:b:c
1 : 0.463 : 0.674
Unit cell volume
983.3 ų
Z
2
Morphology

Crystals elongated on a and tabular on (010). The crystals are either simply or polysynthetically twinned on (001).

Twinning

Polysynthetically twinned on (001).

Type-locality form

On the walls of voids within altered zwieselite crystals or form coronas (up to 1 mm in diameter) around cubic crystals of uraninite.

Comment

from powder diffraction data

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
50.92%
25MnManganeseManganese354.938164.814
20.18%
15PPhosphorusPhosphorus430.974123.896
15.17%
13AlAluminiumAluminium226.98253.964
6.60%
20CaCalciumCalcium140.07840.078
4.91%
1HHydrogenHydrogen181.00818.144
2.22%
Total816.870100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2011-002
  • Whiteiet-(CaMnMn)

In other languages

German
IMA 2011-002 · Whiteit-(CaMnMn)
Italian
Whiteite- · whiteite-(CaMnMn)

Classification

Strunz
10th ed.

8.DH.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.15Whiteite-(CaMnMn)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 2010Chernyatieva, A.P., Krivovichev, S.V., Yakovenchuk, V.N., Pakhomovsky, Y.A. (2010) Crystal chemistry of a new CaMnMn-dominant member of the whiteite group. 20th General Meeting of the IMA (IMA2010), Budapest, Hungary. 716pp.
  2. 2010Grey, I. E., Mumme, W. G., Neville, S. M., Wilson, N. C., Birch, W. D. (2010) Jahnsite-whiteite solid solutions and associated minerals in the phosphate pegmatite at Hagendorf-Süd, Bavaria, Germany. Mineralogical Magazine, 74 (6) 969-978 doi:10.1180/minmag.2010.074.6.969 DOI: 10.1180/minmag.2010.074.6.969
  3. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011. CNMNC Newsletter No 9. Mineralogical Magazine, 75 (4) 2535-2540 doi:10.1180/minmag.2011.075.4.2535 DOI: 10.1180/minmag.2011.075.4.2535
  4. 2012Yakovenchuk, V. N., Keck, E., Krivovichev, S. V., Pakhomovsky, Y. A., Selivanova, E. A., Mikhailova, J. A., Chernyatieva, A. P., Yu. Ivanyuk, G. (2012) Whiteite-(CaMnMn), CaMnMn2Al2[PO4]4(OH)2·8H2O, a new mineral from the Hagendorf-Süd granitic pegmatite, Germany. Mineralogical Magazine, 76 (7) 2761-2771 doi:10.1180/minmag.2012.076.7.09 DOI: 10.1180/minmag.2012.076.7.09
  5. 2015(2015) Whiteite-(CaMnMn). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Whiteite-(CaMnMn) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/whiteite-camnmn-40435},
  note      = {Accessed 2026-05-11}
}