Whiteite-(CaMnFe)

CaMnFe2Al2(PO4)4(OH)2 · 8H2O
IMA status
  • Approved
IMA symbol
Wt-CaMnFe
Also known as
  • IMA2022-072
  • Whiteiet-(CaMnFe)

Where it forms, where it's found

Geological setting

Granitic pegmatite.

Type locality
Hagendorf South Pegmatite
  1. Hagendorf
  2. Waidhaus
  3. Neustadt an der Waldnaab District
  4. Upper Palatinate
  5. Bavaria
  6. Germany

49.6503°, 12.4597°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colourless to light brown to pale yellow
Density
2.80 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 59° · 2V calc = 60.4°
Refractive index
1.608 – 1.624
Surface relief
Moderate
Principal indices
nα 1.608 · nβ 1.612 · nγ 1.624
Pleochroism
Non-pleochroic
Extinction
Y = b.
Michel-Lévy diagramhighlighted lineδ = 0.0160
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]160 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation160 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 14.925(2) Å · b = 7.0100(14) Å · c = 10.053(2) Å
Cell angles
β = 111.31(2) °
Ratio a:b:c
1 : 0.470 : 0.674
Z
2
Morphology

Rod-like crystals, composed of sub-parallel growth of laths only a few micrometres in width. The laths are flattened on (001) and elongated along [010].

Twinning

Twinning by a 180° rotation about [100].

Type-locality form

Sprays and clusters of interlocking rod-like crystals, with diameters of typically 10 to 50 µm and lengths up to ∼ 500 µm.

Comment

Space group: P2/a

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
50.81%
15PPhosphorusPhosphorus430.974123.896
15.13%
26FeIronIron255.845111.690
13.64%
25MnManganeseManganese154.93854.938
6.71%
13AlAluminiumAluminium226.98253.964
6.59%
20CaCalciumCalcium140.07840.078
4.90%
1HHydrogenHydrogen181.00818.144
2.22%
Total818.684100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2022-072
  • Whiteiet-(CaMnFe)

In other languages

German
Whiteit-(CaMnFe)
Italian
Whiteite- · Whiteite-(CaMnFe)

Classification

Strunz
10th ed.

8.DH

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DHWhiteite-(CaMnFe)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 70. European Journal of Mineralogy, 34 (6) 591-601 doi:10.5194/ejm-34-591-2022 DOI: 10.5194/ejm-34-591-2022
  2. 2023Hochleitner, Rupert, Rewitzer, Christian, Grey, Ian E., Mumme, William G., MacRae, Colin M., Kampf, Anthony R., Keck, Erich, Gable, Robert W., Glenn, Alexander M. (2023) Whiteite-(CaMnFe), a new jahnsite-group mineral from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria. European Journal of Mineralogy, 35 (1) 95-103 doi:10.5194/ejm-35-95-2023 DOI: 10.5194/ejm-35-95-2023
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Whiteite-(CaMnFe) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/whiteite-camnfe-470500},
  note      = {Accessed 2026-05-11}
}