Whiteite-(CaMnMg)

CaMn2+Mg2Al2(PO4)4(OH)2 · 8H2O
IMA status
  • Approved
IMA symbol
Wt-CaMnMg
IMA approved
1986
Also known as
  • IMA1986-012
  • Whiteiet-(CaMnMg)

Where it forms, where it's found

Geological setting

Complex granite pegmatite

Type locality
Tip Top Mine
  1. Fourmile
  2. Custer Mining District
  3. Custer County
  4. South Dakota
  5. USA

43.7156°, -103.6694°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Yellow · light lavender · pink
Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

On (001)

Density
2.63 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 74 – 81° · 2V calc = 76°
Refractive index
1.58 – 1.591
Surface relief
Moderate
Principal indices
nα 1.58 · nβ 1.584 · nγ 1.591
Pleochroism
Weak

X = mauve, Y = light mauve, Z = colorless

Dispersion
none
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0110
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]110 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation110 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 14.842(9) Å · b = 6.976(1) Å · c = 10.109(4) Å
Cell angles
β = 112.59(5) °
Ratio a:b:c
1 : 0.470 : 0.681
Z
2
Type-locality form

Dull or etched, yellowish bipyramidal crystals or blebs up to 1.5x0.5x0.5 mm.

Comment

Space group P2/a or Pa.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2615.999415.974
55.05%
15PPhosphorusPhosphorus430.974123.896
16.40%
25MnManganeseManganese154.93854.938
7.27%
13AlAluminiumAluminium226.98253.964
7.14%
12MgMagnesiumMagnesium224.30548.610
6.43%
20CaCalciumCalcium140.07840.078
5.31%
1HHydrogenHydrogen181.00818.144
2.40%
Total755.604100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1986-012
  • Whiteiet-(CaMnMg)

In other languages

German
IMA 1986-012 · Whiteit-(CaMnMg)
Italian
IMA1986-012 · Whiteite- · whiteite-(CaMnMg)
Chinese
磷铝镁锰钙石

Classification

Strunz
10th ed.

8.DH.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.15Whiteite-(CaMnMg)Species
Dana
8th ed.

42.11.03.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.03Whiteite GroupGroup
  • 42.11.03.03Whiteite-(CaMnMg)Species
CIM

19.12.61

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.61Whiteite-(CaMnMg)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 1978Moore, Paul Brian, Ito, Jun (1978) I. Whiteite, a new species, and a proposed nomenclature for the jahnsite-whiteite complex series. II. New data on xanthoxenite. III. Salmonsite discredited. Mineralogical Magazine, 42 (323) 309-323 doi:10.1180/minmag.1978.042.323.01 DOI: 10.1180/minmag.1978.042.323.01
  2. 1986IMA-meeting in Stanford, Abstr. and Progr. (1986), p. 114.
  3. 1989Grice, J. D., Dunn, P. J., Ramik, R. A. (1989) Whiteite-(CaMnMg), a new species from the Tip Top Pegmatite, Custer, South Dakota. The Canadian Mineralogist, 27 (4) 699-702
  4. 1990American Mineralogist (1990): 75: 933.
  5. 2005(2005) Whiteite-(CaMnMg). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Whiteite-(CaMnMg) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/whiteite-camnmg-4278},
  note      = {Accessed 2026-05-11}
}