Zincolivenite

CuZn(AsO4)(OH)
IMA status
  • Approved
IMA symbol
Zoli
IMA approved
2006
Also known as
  • IMA2006-047
  • Zincoliveniet
  • Zincolivenit

Where it forms, where it's found

Geological setting

In the cavities of limonite ores.

Type locality
Agios Konstantinos (Kamariza)
  1. Lavreotiki
  2. East Attica
  3. Attica
  4. Greece
81recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Green · greenish blue
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (010), imperfect on (101)

Fracture
Conchoidal
Density
4.34 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 30° · 2V calc = 31.5°
Refractive index
1.736 – 1.788
Surface relief
High
Principal indices
nα 1.736 · nβ 1.784 · nγ 1.788
Birefringence
0.052
Pleochroism
Weak

X = light bluish green, Y = Z = light blue

Dispersion
r > v, very strong
Extinction
Parallel extinction.
Notes

Orientation: X = b, Y = a, Z = c

Michel-Lévy diagramhighlighted lineδ = 0.0520
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]520 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation520 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#73
Cell parameters
a = 8.5839(15) Å · b = 8.5290(13) Å · c = 5.9696(9) Å
Ratio a:b:c
1 : 0.994 : 0.695
Unit cell volume
437.05 ų
Z
4
Morphology

Observed forms: (120) and (101).

Type-locality form

Prismatic crystals and radial intergrowths.

Comment

Pseudotetragonal metrics

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
28.08%
33AsArsenicArsenic174.92274.922
26.30%
30ZnZincZinc165.38065.380
22.95%
29CuCopperCopper163.54663.546
22.31%
1HHydrogenHydrogen11.0081.008
0.36%
Total284.851100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2006-047
  • Zincoliveniet
  • Zincolivenit

In other languages

German
IMA 2006-047 · Zinkolivenit
Spanish
cincolivenita · Zincolivenita
Italian
zincolivenite
Chinese
鋅橄榄铜矿

Classification

Strunz
10th ed.

8.BB.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.30ZincoliveniteSpecies
Dana
8th ed.

41.06.05.06

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.05— unnamed intermediate level —Group
  • 41.06.05.06ZincoliveniteSpecies

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 1965Mincheva-Stefanova, I., Panchev, B., Bonev, Iv. & Punev, L. (1965): X-ray diffraction determination of chemical composition of intermediate members of the olivenite-adamite series. Izv. Geol. Inst. Bulgar. Akad. Nauk 14, 91-106. (in Bulgarian.)
  2. 1978Toman, K. (1978) Ordering in olivenite–adamite solid solutions. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 34 (3) 715-721 doi:10.1107/s0567740878003933DOI: 10.1107/s0567740878003933
  3. 1979Walenta, K. and Greil, P. (1979): Pseudotetragonaler Cuproadamin. Chemie der Erde 38, 218-222.
  4. 1983Braithwaite, R. S. W. (1983) Infrared spectroscopic analysis of the olivenite-adamite series, and of phosphate substitution in olivenite. Mineralogical Magazine, 47 (342) 51-57 doi:10.1180/minmag.1983.047.342.09 DOI: 10.1180/minmag.1983.047.342.09
  5. 1985Chisholm, J. E. (1985) Cation segregation and the O-H stretching vibration of the olivenite-adamite series. Physics and Chemistry of Minerals, 12 (3) 185-190 doi:10.1007/bf00308212DOI: 10.1007/bf00308212
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zincolivenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zincolivenite-31502},
  note      = {Accessed 2026-05-11}
}