Libethenite

Cu2(PO4)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Lib
Discovered
1823
Also known as
  • Aferesa
  • Aphérèse (of Beudant)
  • Blättricher Olivenmalachit
  • +13 more

History

The mineral takes its name from a Slovak copper town, and the town's story begins long before mineralogy had a vocabulary. Copper was already being mined at Ľubietová in the Bronze Age, and by the Middle Ages the deposit had grown into one of the most important copper sources in central Europe.

In 1379, the settlement was granted the status of a royal town by Louis the Great, and German miners were brought in to work the ore. The German colonists called the town Libethen — the name later anchored both the locality and the mineral. Hungarian usage knew the place as Libetbánya; the Slovak form is Ľubietová. Until 1919, the town sat inside the Kingdom of Hungary.

Ľubietová joined the League of Seven Mining Towns alongside Banská Belá, Banská Bystrica, Banská Štiavnica, Kremnica, Nová Baňa, and Pukanec — a Protestant alliance built on the wealth of central Slovak ore. In 1692, the first modern blast furnace in the Kingdom of Hungary was built in the town. Mining declined through the 18th century, and the settlement lost its urban character and became a village.

The mineral itself was described in 1823 by the German mineralogist August Breithaupt, who named it after the German name of the type locality. Olive-green to dark green orthorhombic crystals of libethenite form in the oxidised zone — the weathered upper layer where copper ore reacts with air and water — of copper deposits like the one beneath Ľubietová.

Outside its type locality, libethenite is best known to collectors from the copper mines of the Katanga Copper Crescent in the Democratic Republic of the Congo, where deposits such as the M'sesa mine near Kambove have yielded sought-after specimens.

Industrial & practical applications

Libethenite has no industrial use. It is too rare to mine for copper — the great copper producers run on chalcopyrite, bornite, chalcocite, and malachite, not on a scarce secondary phosphate of the oxidised zone, the weathered upper layer where copper ore reacts with air and water.

What demand exists is from mineral collectors. The olive-green to dark-green orthorhombic crystals, often arranged in clusters on a host of malachite or limonite, are valued for their colour and crystal form rather than for any extractive purpose. Specimens from the type locality at Ľubietová in Slovakia, and from the M'sesa mine in the Kambove district of the Democratic Republic of the Congo, circulate among collectors and museums as representatives of the species.

Where it forms, where it's found

Geological setting

Polymetallic hydrothermal or deposit

Oxidized zones of copper deposits.

Type locality
Podlipa deposit
  1. Ľubietová
  2. Banská Bystrica District
  3. Banská Bystrica Region
  4. Slovakia

48.7472°, 19.3850°

257recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Light to dark green · blackish green · olive-green · bluish green to light green in transmitted light.
Streak
Light green
Tenacity
brittle
Cleavage
Poor/Indistinct

Very indistinct on (100) and (010).

Fracture
Irregular/Uneven · Conchoidal
Density
3.97 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80 – 90° · 2V calc = 88°
Refractive index
1.701 – 1.79
Surface relief
High
Principal indices
nα 1.701 – 1.704 · nβ 1.743 – 1.747 · nγ 1.787 – 1.79
Birefringence
0.080
Pleochroism
Weak

X= Pale yellowish blue Z= Pale greenish blue

Dispersion
strong r > v
Extinction
XYZ = bca
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#73
Cell parameters
a = 8.062(5) Å · b = 8.384(4) Å · c = 5.881(2) Å
Cell angles
β = 90 °
Ratio a:b:c
1 : 1.040 : 0.729
Unit cell volume
404.27 ų
Z
4
Morphology

Crystals short prismatic or slightly elongated [100] with wedge-shaped terminations; also equant. (110) vertically grooved or striated, and (011) striated parallel to the edge with (111).

Twinning

None observed.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
53.16%
8OOxygenOxygen515.99979.995
33.46%
15PPhosphorusPhosphorus130.97430.974
12.96%
1HHydrogenHydrogen11.0081.008
0.42%
Total239.069100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • As

Synonyms

  • Aferesa
  • Aphérèse (of Beudant)
  • Blättricher Olivenmalachit
  • Blättricher Olivenmalachite
  • Blättriger Olivenmalachit
  • Chinoite
  • Cuivre Phosphaté (of Haüy)
  • Diprismatischer Oliven-Malachit
  • Diprismatischer Olivenmalachit
  • Libetenite
  • Libethkupfererz
  • Octaedrisches Phosphorkupfer
  • Oktaedrisches Phosphorkupfer
  • Oktaedrisches phosphorsaures Kupfer
  • Pseudolibethenite
  • Rhombisches Phosphorkupfer

In other languages

French
Libéthénite
German
Libethenit
Spanish
Libethenita
Italian
libethenite
Japanese
リベセナイト
Chinese
磷銅礦
Russian
Либетенит

Classification

Strunz
10th ed.

8.BB.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.30LibetheniteSpecies
Dana
8th ed.

41.06.06.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.06A2(XO4)ZqType
  • 41.06.06Olivenite GroupGroup
  • 41.06.06.02LibetheniteSpecies
CIM

19.2.1

  • 19PhosphatesClass
  • 19.2Phosphates of CuGroup
  • 19.2.1LibetheniteSpecies

Group, growth & confusion

In the same group
6 members
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1789Werner (1789) Bergmaennusches Journal, Freiberg (Neues Bergmannische Journal): 382, 385 (as Olivenerz).
  2. 1813Hausmann, Johann Friedrich Ludwig (1813) Handbuch der Mineralogie (1st ed.). Vandenhoeck und Ruprecht.
  3. 1821Leonhard, K.C. (1821) Handbuch der Oryktognosie. First edition, Heidelberg: 143 (as Octaedrisches Phosphorkupfer).
  4. 1823Breithaupt, August (1823) Vollständige Charakteristik des Mineral-Systems (1st ed.). Arnoldischen Buchhandlung.
  5. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Libethenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/libethenite-2394},
  note      = {Accessed 2026-05-11}
}