Pickeringite

MgAl2(SO4)4 · 22H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pkg
Discovered
1844
Also known as
  • Dumreicherit
  • Magnesia Alum
  • Magnesia-Alaun
  • +9 more

Where it forms, where it's found

Geological setting

Common mineral formed by oxidation of pyrite in aluminous rocks, coal seams, caves, fumaroles, ore veins in arid regions.

Type locality
Cerros Pintados
  1. Tamarugal Province
  2. Tarapacá
  3. Chile

-20.6294°, -69.6572°

243recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Colourless to white · light yellow · pale pink · orange · gray · colourless in transmitted light
Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

On (010) poor.

Fracture
Conchoidal
Density
1.73 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60° · 2V calc = 80°
Refractive index
1.475 – 1.483
Surface relief
Low
Principal indices
nα 1.475 · nβ 1.480 · nγ 1.483
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 20.8 Å · b = 24.2 Å · c = 6.18 Å
Cell angles
β = 95 °
Ratio a:b:c
1 : 1.163 : 0.297
Z
4
Morphology

Crystals acicular [001]; distinctly terminated crystals rare. Radial or matted aggregates of hair-like crystals; tufted; spheroidal; as incrustations or effloresences; asbestiform. Larger crystals may be hollow or contain bubbles of liquid or gas.

Type-locality form

Masses, composed of long parallel fibers.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3815.999607.962
70.79%
16SSulfurSulfur432.060128.240
14.93%
13AlAluminiumAluminium226.98253.964
6.28%
1HHydrogenHydrogen441.00844.352
5.17%
12MgMagnesiumMagnesium124.30524.305
2.83%
Total858.823100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • Fe
  • Co

Synonyms

  • Dumreicherit
  • Magnesia Alum
  • Magnesia-Alaun
  • Magnesium-Halotrichite
  • Picralluminite
  • Picroallumogene
  • Pikroalumogen
  • Seelandit
  • Seelandita
  • Sesqui-Magnesia-alaun
  • Sonomaite
  • Talkerde-Alaun

In other languages

French
Pickeringite
German
Pickeringit
Spanish
Pickeringita
Italian
Pickeringite
Japanese
苦土毛礬

Classification

Strunz
10th ed.

7.CB.85

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.85PickeringiteSpecies
Dana
8th ed.

29.07.03.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.07AB2(XO4)4·H2OType
  • 29.07.03Halotrichite Group (Monoclinic with 22 H2O)Group
  • 29.07.03.01PickeringiteSpecies
CIM

25.3.18

  • 25SulphatesClass
  • 25.3Sulphates of MgGroup
  • 25.3.18PickeringiteSpecies

Group, growth & confusion

Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Mitteregger, Josef; Brunlechner, August (1891): Ein neues Mineral. Carinthia II, 81: 52. https://www.zobodat.at/pdf/CAR_81_0052.pdf
  2. 1844Hayes, A.A. (1844) Description and analysis of pickeringite, a native magnesian alum. American Journal of Science and Arts: 46: 360-362.
  3. 1867How, H. (1867) On magnesia-alum, or pickeringite, containing a little nickel and cobalt, occurring in slate in Hants Co. Nova Scotian Institute of Natural Science: 1: 85-87.
  4. 1868Dana, James D., Brush, George Jarvis (1868) A System of Mineralogy (5th ed.). p.882
  5. 1876Roster (1876) Boll. com. geol. Ital.: 302 (as Picroallumogene).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pickeringite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pickeringite-3204},
  note      = {Accessed 2026-05-11}
}