Halotrichite

Fe2+Al2(SO4)4 · 22H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hth
Discovered
1839
Also known as
  • Alotrichit
  • Alotrichita
  • Butter-Rock
  • +9 more

Where it forms, where it's found

418recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless to white · yellowish · greenish · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

On (010), poor.

Fracture
Conchoidal
Density
1.89 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 35° · 2V calc = 78°
Refractive index
1.48 – 1.49
Surface relief
Low
Principal indices
nα 1.48 · nβ 1.486 · nγ 1.49
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#8
Cell parameters
a = 20.51 Å · b = 24.29 Å · c = 6.18 Å
Cell angles
β = 100.99 °
Ratio a:b:c
1 : 1.184 : 0.301
Morphology

Crystals acicular [001]; distinctly terminated crystals rare. Radial or matted aggregates of hair-like crystals; tufted; spheroidal; as incrustations or efflorescences; asbestiform. Larger crystals may be hollow or contain bubbles of liquid or gas.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3815.999607.962
68.28%
16SSulfurSulfur432.060128.240
14.41%
26FeIronIron155.84555.845
6.27%
13AlAluminiumAluminium226.98253.964
6.06%
1HHydrogenHydrogen441.00844.352
4.98%
Total890.363100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Alotrichit
  • Alotrichita
  • Butter-Rock
  • Eisenalaun
  • Federalaun vom Freyenwalde
  • Halotrichine
  • Halotrichit (of Glocker)
  • Halotrichita
  • Halotrichite (of Glocker)
  • Hversalt
  • Iron Alum
  • Mountain Butter

In other languages

French
Halotrichite
German
Eisenalaun · Federalaun · Haarsalz · Halotrichit
Spanish
Halotriquita
Italian
alotrichite
Russian
Галотрихит
Arabic
هالوتريتشيت

Classification

Strunz
10th ed.

7.CB.85

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.85HalotrichiteSpecies
Dana
8th ed.

29.07.03.02

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.07AB2(XO4)4·H2OType
  • 29.07.03Halotrichite Group (Monoclinic with 22 H2O)Group
  • 29.07.03.02HalotrichiteSpecies
CIM

25.11.26

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.26HalotrichiteSpecies

Group, growth & confusion

Often grow together
5 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Sheveleva, R.M., Nazarova, M.A., Nuzhdaev, A.A., Zhegunov, P.S., Zhitova, E.S. (2023): Distribution and chemical composition of halotrichite in geothermal fields of Kamchatka. Vestnik Kamchatskoy regional'noy assotsiatsii «Uchebno-nauchnyy tsentr». Seriya: Nauki o Zemle, 58, 5-16.
  2. 1802Klaproth, M. H. (1802) LXXXI. Untersuchung des Federalauns v. Freienwalde. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.102-103.
  3. 1839Glocker, E.F. (1839) 18. Halotrichit. in Grundrib der Mineralogie, mit Einschlub der Geognosie und Petrefactenkunde, Schrag (Nürnberg), 691-691. (as Halotrichit)
  4. 1843Forchhammer (1843) Jahresbericht über die Fortschritte der Chemie und verwandter Teile anderer Wissenschaften, 23. J. Ricker, F. Vieweg und Sohn. 263
  5. 1849Scacchi (1849) Mem. geol. camp. Nap.: 84 (as Halotrichine).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Halotrichite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/halotrichite-1809},
  note      = {Accessed 2026-05-11}
}