Arrojadite-(BaNa)

BaNa3(NaCa)Fe2+13Al(PO4)11(PO3OH)(OH)2
IMA status
  • Approved
IMA symbol
Ajd-BaNa
IMA approved
2014
Also known as
  • Arrojadiet-(BaNa)
  • Arrojaditt-(BaNa)
  • IMA2014-071

Where it forms, where it's found

Geological setting

Pegmatite

Type locality
Luna pegmatitic dyke
  1. Dorio
  2. Lecco Province
  3. Lombardy
  4. Italy

46.1088°, 9.3307°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Greenish · yellowish
Tenacity
brittle
Cleavage
Distinct/Good

parallel to (110)

Fracture
Irregular/Uneven
Density
3.54 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 44° · 2V calc = 45°
Refractive index
1.656 – 1.664
Surface relief
High
Principal indices
nα 1.656 · nβ 1.660 · nγ 1.664
Dispersion
moderate
Tropism
Anisotropic
UV response
Non-fluorescent under both short-wave (254 nm) and long-wave (366 nm) ultraviolet light
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 16.4984(6) Å · b = 10.0228(3) Å · c = 24.648(1) Å
Cell angles
β = 105.850(4) °
Ratio a:b:c
1 : 0.608 : 1.494
Unit cell volume
3920.8 ų
Z
4
Morphology

Masses, or rough crystals up to 4–5 cm in diameter

Type-locality form

Greenish or yellowish translucent masses, or rough crystals up to 4–5 cm in diameter hosted by albite.

Comment

Tomes et al. 2018 give the space group as Cc.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5015.999799.950
36.41%
26FeIronIron1355.845725.985
33.04%
15PPhosphorusPhosphorus1230.974371.688
16.92%
56BaBariumBarium1137.327137.327
6.25%
11NaSodiumSodium422.99091.960
4.19%
20CaCalciumCalcium140.07840.078
1.82%
13AlAluminiumAluminium126.98226.982
1.23%
1HHydrogenHydrogen31.0083.024
0.14%
Total2196.994100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arrojadiet-(BaNa)
  • Arrojaditt-(BaNa)
  • IMA2014-071

In other languages

German
Arrojadit-(BaNa) · IMA 2014-071
Italian
arrojadite-(BaNa)

Classification

Strunz
10th ed.

8.BF.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BFWith medium-sized and large cations, (OH, etc.):RO4< 0.5:1Group
  • 8.BF.05Arrojadite-(BaNa)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. (revised 2018) http://www.handbookofmineralogy.com/pdfs/arrojadite-(BaNa).pdf (for some optical data)
  2. 2015Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. Mineralogical Magazine, 79 (1) 51-58 doi:10.1180/minmag.2015.079.1.05DOI: 10.1180/minmag.2015.079.1.05
  3. 2016Vignola, Pietro, Hatert, Frédéric, Baijot, Maxime, Dal Bo, Fabrice, Andò, Sergio, Bersani, Danilo, Pavese, Alessandro, Risplendente, Andrea, Vanini, Francesco (2016) Arrojadite-(BaNa), BaNa3(Na,Ca)Fe2+13Al(PO4)11(PO3OH)(OH)2, A New Phosphate Mineral From the Luna Albite Pegmatite, Dorio Commune, Lecco Province, Italy. The Canadian Mineralogist, 54 (4) 1021-1032 doi:10.3749/canmin.1500100DOI: 10.3749/canmin.1500100
  4. 2018Tomes, H.E., Di Cecco, V.E., Tait, K.T., Cámara, F. (2018) Crystal Structure of Near-Endmember Arrojadite-(BaNa) from Big Fish River, Yukon, Canada. The Canadian Mineralogist: 56(6): 923–938.
  5. 2022(2022) Arrojadite-(BaNa). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arrojadite-(BaNa) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arrojadite-bana-29414},
  note      = {Accessed 2026-05-11}
}