Arrojadite-(PbFe)

PbFe2+(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2
IMA status
  • Approved
IMA symbol
Ajd-PbFe
IMA approved
2006
Also known as
  • Arrojadiet-(PbFe)
  • Arrojaditt-(PbFe)
  • IMA2005-056

Where it forms, where it's found

Geological setting

Granite pegmatite.

Type locality
Sapucaia mine
  1. Sapucaia do Norte
  2. Galiléia
  3. Minas Gerais
  4. Brazil

-18.9008°, -41.4844°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Pale honey
Streak
White
Density
3.596 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 58.2° · 2V calc = 47°
Refractive index
1.6585 – 1.668
Surface relief
High
Principal indices
nα 1.6585 · nβ 1.6600 · nγ 1.6680
Pleochroism
Not Visible
Dispersion
r > v.
Extinction
x = b.
Michel-Lévy diagramhighlighted lineδ = 0.0095
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]95 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation95 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#3
Cell parameters
a = 16.4304(9) Å · b = 9.9745(5) Å · c = 24.5869(13) Å
Cell angles
β = 105.485 °
Ratio a:b:c
1 : 0.607 : 1.496
Type-locality form

Clear, up to millimeter-sized anhedral, corroded, isolated crystals in a groundmass of triphylite with some chloritized biotite and albite.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5015.999799.950
35.14%
26FeIronIron1455.845781.830
34.34%
15PPhosphorusPhosphorus1230.974371.688
16.33%
82PbLeadLead1207.200207.200
9.10%
11NaSodiumSodium222.99045.980
2.02%
20CaCalciumCalcium140.07840.078
1.76%
13AlAluminiumAluminium126.98226.982
1.18%
1HHydrogenHydrogen31.0083.024
0.13%
Total2276.732100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arrojadiet-(PbFe)
  • Arrojaditt-(PbFe)
  • IMA2005-056

In other languages

German
Arrojadit-(PbFe) · IMA 2005-056
Italian
arrojadite-(PbFe)

Classification

Strunz
10th ed.

8.BF.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BFWith medium-sized and large cations, (OH, etc.):RO4< 0.5:1Group
  • 8.BF.05Arrojadite-(PbFe)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 2006Camara, F. (2006) The arrojadite enigma: I. A new formula and a new model for the arrojadite structure. American Mineralogist, 91 (8) 1249-1259 doi:10.2138/am.2006.2189 DOI: 10.2138/am.2006.2189
  2. 2006Chopin, Christian, Oberti, Roberta, Cámara, Fernando (2006) The arrojadite enigma: II. Compositional space, new members, and nomenclature of the group. American Mineralogist, 91 (8). 1260-1270 doi:10.2138/am.2006.2190DOI: 10.2138/am.2006.2190
  3. 2022(2022) Arrojadite-(PbFe). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arrojadite-(PbFe) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arrojadite-pbfe-29064},
  note      = {Accessed 2026-05-11}
}