Arrojadite-(KFe)

(KNa)Fe2+(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ajd-KFe
Discovered
1925
Also known as
  • Arrojadiet-(KFe)
  • Arrojadit
  • Arrojadita
  • +5 more

Where it forms, where it's found

Type locality
Serra Branca pegmatite
  1. Pedra Lavrada
  2. Paraíba
  3. Brazil

-6.8332°, -36.5180°

46recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Olive-green
Streak
white
Tenacity
brittle
Cleavage
Distinct/Good

On (100) good; on (010), distinct.

Fracture
Irregular/Uneven
Density
3.527 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 80 – 86° · 2V calc = 84°
Refractive index
1.664 – 1.675
Surface relief
High
Principal indices
nα 1.664 · nβ 1.670 · nγ 1.675
Pleochroism
Visible

X = colorless; Y = colorless to pale green; Z = pale yellow-green.

Dispersion
strong
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0110
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]110 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation110 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
Cc
Cell parameters
a = 16.53 Å · b = 10.05 Å · c = 24.75 Å
Cell angles
β = 105.65 °
Ratio a:b:c
1 : 0.608 : 1.497
Z
4
Morphology

As cleavable masses to 15 cm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5015.999799.950
37.53%
26FeIronIron1455.845781.830
36.68%
15PPhosphorusPhosphorus1230.974371.688
17.44%
11NaSodiumSodium322.99068.970
3.23%
20CaCalciumCalcium140.07840.078
1.88%
19KPotassiumPotassium139.09839.098
1.83%
13AlAluminiumAluminium126.98226.982
1.27%
1HHydrogenHydrogen31.0083.024
0.14%
Total2131.620100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arrojadiet-(KFe)
  • Arrojadit
  • Arrojadita
  • Arrojaditt-(KFe)
  • Arrojardit
  • Headdenit
  • Headdenita
  • Headdenite

In other languages

German
Arrojadit-(KFe)
Italian
Arrojadite · Arrojadite- · Arrojadite-(KFe)

Classification

Strunz
10th ed.

8.BF.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BFWith medium-sized and large cations, (OH, etc.):RO4< 0.5:1Group
  • 8.BF.05Arrojadite-(KFe)Species
Dana
8th ed.

41.07.02.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.07(AB)7(XO4)4ZqType
  • 41.07.02— unnamed intermediate level —Group
  • 41.07.02.01Arrojadite-(KFe)Species
CIM

19.12.53

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.53Arrojadite-(KFe)Species

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1942Mason, Brian (1942) Some iron-manganese phosphate minerals from the pegmatite at Hühnerkobel in Bavaria. Geologiska Föreningen i Stockholm Förhandlingar, 64 (3) 335-340 doi:10.1080/11035894209446083DOI: 10.1080/11035894209446083
  2. 1942Guimarães, Djalma (1942) Arrojadite, a new mineral of the wagnerite group. Boletim da Faculdade de Filosofia, Ciências e Letras da Universidade de São Paulo. Mineralogia 5, 3-16 doi:10.11606/bmffclusp.v0i5.121334DOI: 10.11606/bmffclusp.v0i5.121334
  3. 1946Eriksson (1946) Arkiv för Kemi, Mineralogi och Geologi, Stockholm: 23A, no. 8. [as Hühnerkobelite]
  4. 1950Lindberg, Marie Louise (1950) Arrojadite, hühnerkobelite, and graftonite. American Mineralogist, 35 (1-2) 59-76
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arrojadite-(KFe) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arrojadite-kfe-351},
  note      = {Accessed 2026-05-11}
}