Where it forms, where it's found
- Geological setting
In phengitic quartzite.
- Type locality
- Groppera Alp
- Madesimo
- Sondrio Province
- Lombardy
- Italy
46.4305°, 9.3709°
7recorded occurrences
Physical
Optical
- Optical type
- Biaxial
- Pleochroism
- Not Visible
- Extinction
- Extinction angle is about 25 deg with respect to the elongation.
- UV response
- None
Crystallography
- Cell parameters
- a = 16.406(5) Å · b = 9.945(3) Å · c = 24.470(5) Å
- Cell angles
- β = 105.73(2) °
- Ratio a:b:c
- 1 : 0.606 : 1.492
- Z
- 4
- Type-locality form
Small grayish-green lump, ~4 cm in size, somewhat similar to massive apatite, directly included in the rock.
Crystal structure
Chemical composition
Synonyms
- Arrojadite-(BaFe)
- Ba-arrojadite
- IMA1994-033
- Sigismundiet
In other languages
- German
- Arrojadit-(BaFe) · IMA 1994-033 · Sigismundit
- Italian
- Arrojadite-(BaFe) · Sigismundite
Classification
Strunz
10th ed.8.BF
- 8Phosphates, Arsenates, VanadatesClass
- 8.BPhosphates, etc., with additional anions, without H2ODivision
- 8.BFWith medium-sized and large cations, (OH, etc.):RO4< 0.5:1Group
- 8.BFSigismunditeSpecies
Group, growth & confusion
Arrojadite-(BaNa)BaNa3(NaCa)Fe2+13Al(PO4)11(PO3OH)(OH)2Mineral—
Arrojadite-(KFe)(KNa)Fe2+(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2Mineral—- Arrojadite-(KNa)KNa3(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2Mineral—
- Arrojadite-(PbFe)PbFe2+(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2Mineral—
- Arrojadite-(SrFe)SrFe2+(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2Mineral—
Dickinsonite-(KMnNa)K(NaMn)CaNa3AlMn13(PO4)12(OH)2Mineral—- Fluorarrojadite-(BaFe)Na2CaBaFe2+Fe2+13Al(PO4)11(PO3OH)F2Mineral—
Fluorarrojadite-(BaNa)BaNa4CaFe13Al(PO4)11(PO3OH)F2Mineral—- Fluorcarmoite-(BaNa)Ba◻Na2Na2◻CaMg13Al(PO4)11(PO3OH)F2Mineral—
- Manganoarrojadite-(KNa)KNa5MnFe13Al(PO4)11(PO3OH)(OH)2Mineral—
Literature, links & citation
Citations
- 1969von Knorring, O. (1969) A note on the phosphate mineralisation at the Buranga pegmatite, Rwanda. Bulletin du Service Géologique de la République du Rwanda: 5: 42-45. (as barian arrojadite).
- 1969Bertossa, A. (1969) Addendum à l'inventaire des minéraux du Rwanda. Bulletin du Service Géologique de la République du Rwanda: 5: 1-4. (as Ba-arrojadite).
- 1996Demartin, F., Gramaccioli, C. M., Pilati, T., Sciesa, E. (1996) Sigismundite, (Ba,K,Pb)Na3(Ca,Sr)(Fe,Mg,Mn)14Al(OH)2(PO4)12, a new Ba-rich member of the arrojadite group from Spluga Valley, Italy. The Canadian Mineralogist, 34 (4) 827-834
- 1998Daltry, V.D.C., von Knorring, O. (1998) Type-mineralogy of Rwanda with particular reference to the Buranga pegmatite. Geologica Belgica: 1: 9-15. https://popups.uliege.be/1374-8505/index.php?id=1593
- 2006Camara, F. (2006) The arrojadite enigma: I. A new formula and a new model for the arrojadite structure. American Mineralogist, 91 (8) 1249-1259 doi:10.2138/am.2006.2189 DOI: 10.2138/am.2006.2189
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Sigismundite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/sigismundite-7294},
note = {Accessed 2026-05-11}
}