Sigismundite

BaFe2+(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2
IMA status
  • Approved
IMA symbol
Ajd-BaFe
IMA approved
1994
Also known as
  • Arrojadite-(BaFe)
  • Ba-arrojadite
  • IMA1994-033
  • +1 more

Where it forms, where it's found

Geological setting

In phengitic quartzite.

Type locality
Groppera Alp
  1. Madesimo
  2. Sondrio Province
  3. Lombardy
  4. Italy

46.4305°, 9.3709°

7recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Greasy (Oily)
Transparency
Translucent
Colour
Grayish-green
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Two different cleavage planes, one more distinct than the other, making an angle of about 110 degrees.

Fracture
Irregular/Uneven
Density
3.544 g/cm³

Optical

Optical type
Biaxial
Pleochroism
Not Visible
Extinction
Extinction angle is about 25 deg with respect to the elongation.
UV response
None

Crystallography

Crystal system
Monoclinic
Space group
Cc
Cell parameters
a = 16.406(5) Å · b = 9.945(3) Å · c = 24.470(5) Å
Cell angles
β = 105.73(2) °
Ratio a:b:c
1 : 0.606 : 1.492
Z
4
Type-locality form

Small grayish-green lump, ~4 cm in size, somewhat similar to massive apatite, directly included in the rock.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5015.999799.950
36.25%
26FeIronIron1455.845781.830
35.43%
15PPhosphorusPhosphorus1230.974371.688
16.84%
56BaBariumBarium1137.327137.327
6.22%
11NaSodiumSodium222.99045.980
2.08%
20CaCalciumCalcium140.07840.078
1.82%
13AlAluminiumAluminium126.98226.982
1.22%
1HHydrogenHydrogen31.0083.024
0.14%
Total2206.859100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arrojadite-(BaFe)
  • Ba-arrojadite
  • IMA1994-033
  • Sigismundiet

In other languages

German
Arrojadit-(BaFe) · IMA 1994-033 · Sigismundit
Italian
Arrojadite-(BaFe) · Sigismundite

Classification

Strunz
10th ed.

8.BF

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BFWith medium-sized and large cations, (OH, etc.):RO4< 0.5:1Group
  • 8.BFSigismunditeSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1969von Knorring, O. (1969) A note on the phosphate mineralisation at the Buranga pegmatite, Rwanda. Bulletin du Service Géologique de la République du Rwanda: 5: 42-45. (as barian arrojadite).
  2. 1969Bertossa, A. (1969) Addendum à l'inventaire des minéraux du Rwanda. Bulletin du Service Géologique de la République du Rwanda: 5: 1-4. (as Ba-arrojadite).
  3. 1996Demartin, F., Gramaccioli, C. M., Pilati, T., Sciesa, E. (1996) Sigismundite, (Ba,K,Pb)Na3(Ca,Sr)(Fe,Mg,Mn)14Al(OH)2(PO4)12, a new Ba-rich member of the arrojadite group from Spluga Valley, Italy. The Canadian Mineralogist, 34 (4) 827-834
  4. 1998Daltry, V.D.C., von Knorring, O. (1998) Type-mineralogy of Rwanda with particular reference to the Buranga pegmatite. Geologica Belgica: 1: 9-15. https://popups.uliege.be/1374-8505/index.php?id=1593
  5. 2006Camara, F. (2006) The arrojadite enigma: I. A new formula and a new model for the arrojadite structure. American Mineralogist, 91 (8) 1249-1259 doi:10.2138/am.2006.2189 DOI: 10.2138/am.2006.2189
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sigismundite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sigismundite-7294},
  note      = {Accessed 2026-05-11}
}