Arrojadite-(KNa)

KNa3(CaNa2)Fe2+13Al(PO4)11(PO3OH)(OH)2
IMA status
  • Approved
IMA symbol
Ajd-KNa
IMA approved
2005
Also known as
  • Arrojadiet-(KNa)
  • Arrojaditt-(KNa)
  • IMA2005-047

Where it forms, where it's found

Geological setting

In open fractures in siderite-rich Lower Cretaceous sandstones. From low-salinity fluids, under very low-grade metamorphic conditions, at minimum temperatures of 180-200 C.

Type locality
Rapid Creek
  1. Dawson mining district
  2. Yukon
  3. Canada

68.5400°, -136.7996°

4recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Yellow

Optical

Optical type
Biaxial (+) · 2V measured = 87.8° · 2V calc = 85°
Refractive index
1.651 – 1.662
Surface relief
High
Principal indices
nα 1.651 · nβ 1.656 · nγ 1.662
Pleochroism
Weak

Very weak. Y = colorless; X = Z = pale yellow.

Dispersion
r << v.
Extinction
X = b; Y ≈ c.
Notes

Absorption: Y < X ≈ Z.

Michel-Lévy diagramhighlighted lineδ = 0.0110
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]110 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation110 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#3
Cell parameters
a = 16.552 Å · b = 10.0529 Å · c = 24.6477 Å
Cell angles
β = 106.509 °
Ratio a:b:c
1 : 0.607 : 1.489
Type-locality form

Clear, yellow, mm-sized euhedral crystals. Stout, more-or-less platy prisms.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5015.999799.950
37.70%
26FeIronIron1355.845725.985
34.22%
15PPhosphorusPhosphorus1230.974371.688
17.52%
11NaSodiumSodium522.990114.950
5.42%
20CaCalciumCalcium140.07840.078
1.89%
19KPotassiumPotassium139.09839.098
1.84%
13AlAluminiumAluminium126.98226.982
1.27%
1HHydrogenHydrogen31.0083.024
0.14%
Total2121.755100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Arrojadiet-(KNa)
  • Arrojaditt-(KNa)
  • IMA2005-047

In other languages

German
Arrojadit-(KNa) · IMA 2005-047
Italian
arrojadite-(KNa)

Classification

Strunz
10th ed.

8.BF.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BFWith medium-sized and large cations, (OH, etc.):RO4< 0.5:1Group
  • 8.BF.05Arrojadite-(KNa)Species

Group, growth & confusion

Literature, links & citation

Citations
  1. 2006Camara, F. (2006) The arrojadite enigma: I. A new formula and a new model for the arrojadite structure. American Mineralogist, 91 (8) 1249-1259 doi:10.2138/am.2006.2189 DOI: 10.2138/am.2006.2189
  2. 2006Chopin, Christian, Oberti, Roberta, Cámara, Fernando (2006) The arrojadite enigma: II. Compositional space, new members, and nomenclature of the group. American Mineralogist, 91 (8). 1260-1270 doi:10.2138/am.2006.2190DOI: 10.2138/am.2006.2190
  3. 2022(2022) Arrojadite-(KNa). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arrojadite-(KNa) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arrojadite-kna-28959},
  note      = {Accessed 2026-05-11}
}