Arthurite

CuFe3+2(AsO4)2(OH)2 · 4H2O
IMA status
  • Approved
IMA symbol
Atu
Discovered
1954
IMA approved
1964
Also known as
  • Arthuriet
  • Arthuritt
  • Authurit
  • +3 more

Where it forms, where it's found

Geological setting

Formed by alteration of arsenopyrite or enargite.

Type locality
Hingston Down Consols
  1. Clitters United Mines
  2. Gunnislake
  3. Calstock
  4. Cornwall
  5. England
  6. UK

50.5214°, -4.2461°

38recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Apple-green · emerald-green · pale olive-green.
Streak
(not reported)
Cleavage

(not reported)

Density
3.2 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V calc = 86°
Refractive index
1.736 – 1.796
Surface relief
High
Principal indices
nα 1.736 · nβ 1.767 · nγ 1.796
Pleochroism
Weak

X = colorless to pale green; Y = gray-green; Z = olive-green.

Dispersion
r > v
Luminescence
None
Michel-Lévy diagramhighlighted lineδ = 0.0600
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]600 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation600 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 10.09 Å · b = 9.62 Å · c = 5.55 Å
Cell angles
β = 92.2 °
Ratio a:b:c
1 : 0.953 : 0.550
Z
2
Type-locality form

Apple-green crusts

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
40.06%
33AsArsenicArsenic274.922149.844
26.80%
26FeIronIron255.845111.690
19.98%
29CuCopperCopper163.54663.546
11.36%
1HHydrogenHydrogen101.00810.080
1.80%
Total559.146100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • P
  • S

Synonyms

  • Arthuriet
  • Arthuritt
  • Authurit
  • Authurita
  • Authurite
  • IMA1964-002

In other languages

French
arthurite
German
Arthurit · IMA 1964-002
Spanish
Arthurita · Authurita
Italian
Arthurite
Chinese
水砷铁铜石

Classification

Strunz
10th ed.

8.DC.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.15ArthuriteSpecies
Dana
8th ed.

42.11.20.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.20— unnamed intermediate level —Group
  • 42.11.20.02ArthuriteSpecies
CIM

20.1.16

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.1Arsenates of CuGroup
  • 20.1.16ArthuriteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1964Davis, R. J., Hey, M. H. (1964) Arthurite, a new copper—iron arsenate from Cornwall. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (266) 937-941 doi:10.1180/minmag.1964.033.266.01 DOI: 10.1180/minmag.1964.033.266.01
  2. 1965Fleischer, Michael (1965) New Mineral Names. American Mineralogist, 50 (3-4) 519-522
  3. 1969Clark, A.H., Sillitoe, R.H. (1969) Arthurite from Potrerillos, Atacama Province, Chile. Mineralogical Magazine, 37 (288) 519-520 doi:10.1180/minmag.1969.037.288.14 DOI: 10.1180/minmag.1969.037.288.14
  4. 1969Davis, R. J., Hey, M. H. (1969) The cell-contents of arthurite redetermined. Mineralogical Magazine, 37 (288) 520-521 doi:10.1180/minmag.1969.037.288.15 DOI: 10.1180/minmag.1969.037.288.15
  5. 1970Fleischer, M., Nickel, E.H. (1970) New mineral names. American Mineralogist: 55: 1810-1818.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Arthurite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/arthurite-376},
  note      = {Accessed 2026-05-11}
}