Whitmoreite

Fe2+Fe3+2(PO4)2(OH)2 · 4H2O
IMA status
  • Approved
IMA symbol
Whm
Discovered
1974
IMA approved
1974
Also known as
  • IMA1974-009
  • Whitmoreiet

Where it forms, where it's found

Geological setting

Pegmatite. Hydrothermal alteration of triphylite.

Secondary mineral in complex zoned granitic pegmatites.

Type locality
Palermo No. 1 Mine
  1. Groton
  2. Grafton County
  3. New Hampshire
  4. USA

43.7513°, -71.8896°

43recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellow-brown · green-brown
Tenacity
brittle
Cleavage
Imperfect/Fair

Fair on (100)

Density
2.87 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60 – 65° · 2V calc = 62°
Refractive index
1.67 – 1.85
Surface relief
High
Principal indices
nα 1.670 – 1.676 · nβ 1.712 – 1.725 · nγ 1.745 – 1.850
Pleochroism
Visible

X=Y= light greenish brown to yellow Z= dark greenish brown to yellowish green

Dispersion
weak
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.1245
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1245 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1245 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 10 Å · b = 9.73(2) Å · c = 5.471(8) Å
Cell angles
β = 93.8 °
Ratio a:b:c
1 : 0.973 : 0.547
Z
2
Morphology

Uncommon as pseudo-orthorhombic crystals, prismatic to acicular with chisel shape terminations. In fans, radiating sprays or balls. Observed forms include: a(100), m(110), s(011), t(021), and u(112).

Twinning

Common by reflection on (100)

Type-locality form

Acicular crystals with a length to width ratio of 5 to 10, and a length of 0.1 to 2.0 mm. The crystals form fans and sprays. Occasionally as isolated individuals. Typically occurs as a small spheric core from which small, thin crystals radiate.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
48.32%
26FeIronIron355.845167.535
36.14%
15PPhosphorusPhosphorus230.97461.948
13.36%
1HHydrogenHydrogen101.00810.080
2.18%
Total463.549100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn

Synonyms

  • IMA1974-009
  • Whitmoreiet

In other languages

German
IMA 1974-009 · Whitmoreit
Spanish
Whitmoreíta
Italian
Whitmoreite

Classification

Strunz
10th ed.

8.DC.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.15WhitmoreiteSpecies
Dana
8th ed.

42.11.20.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.20— unnamed intermediate level —Group
  • 42.11.20.01WhitmoreiteSpecies
CIM

19.13.6

  • 19PhosphatesClass
  • 19.13Phosphates of Fe aloneGroup
  • 19.13.6WhitmoreiteSpecies

Group, growth & confusion

Often grow together
7 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1974Moore, Paul B., Kampf, Anthony R., Irving, Anthony J. (1974) Whitmoreite, Fe2+Fe3+2(OH)2(H2O)4[PO4]2, a new species: Its description and atomic arrangement. American Mineralogist, 59 (9-10) 900-905
  2. 2000Anthony, John Williams, Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. (2000) Handbook of Mineralogy Vol. 4 - Arsenates, phosphates, vanadates. Mineral Data Publishing, Tucson, Arizona.
  3. 2003Frost, Ray L., Duong, L., Martens, W. (2003) Molecular assembly in secondary minerals – Raman spectroscopy of the arthurite group species arthurite and whitmoreite. Neues Jahrbuch für Mineralogie - Monatshefte, 2003 (5) 223-240 doi:10.1127/0028-3649/2003/2003-0223DOI: 10.1127/0028-3649/2003/2003-0223
  4. 2005(2005) Whitmoreite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Whitmoreite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/whitmoreite-4281},
  note      = {Accessed 2026-05-11}
}