Calcioferrite

Ca4MgFe3+4(PO4)6(OH)4 · 12H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cfr
Discovered
1858
Also known as
  • Calcioferriet
  • Calcoferrit

Where it forms, where it's found

Geological setting

Tertiary clay

Phosphatic clay

Type locality
Battenberg
  1. Leiningerland
  2. Bad Dürkheim
  3. Rhineland-Palatinate
  4. Germany
11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Sulphur-yellow · greenish yellow to green · yellowish white · yellow in transmitted light.
Streak
Sulphur-yellow
Tenacity
brittle
Cleavage
Perfect

One perfect parallel to the foliation; another, interrupted, perpendicular to the first; a third, also interrupted, oblique to the first.

Density
2.51 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70 – 80° · 2V calc = 72°
Refractive index
1.572 – 1.612
Surface relief
Moderate
Principal indices
nα 1.572 – 1.604 · nβ 1.579 – 1.61 · nγ 1.583 – 1.612
Dispersion
r < v strong
Extinction
Z = b; X ∧ c = 61.5°.
Michel-Lévy diagramhighlighted lineδ = 0.0095
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]95 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation95 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 10.34 Å · b = 24.2 Å · c = 6.31 Å
Cell angles
β = 91.5 °
Ratio a:b:c
1 : 2.340 : 0.610
Z
2
Morphology

Crystals flattened on [010]. Forms parallel or radiating groups; foliated; nodular or reniform; massive.

Type-locality form

Nodules

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4015.999639.960
50.71%
26FeIronIron455.845223.380
17.70%
15PPhosphorusPhosphorus630.974185.844
14.72%
20CaCalciumCalcium440.078160.312
12.70%
1HHydrogenHydrogen281.00828.224
2.24%
12MgMagnesiumMagnesium124.30524.305
1.93%
Total1262.025100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calcioferriet
  • Calcoferrit

In other languages

German
Calcioferrit
Spanish
Calcioferrita
Italian
Calcioferrite

Classification

Strunz
10th ed.

8.DH.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.25CalcioferriteSpecies
Dana
8th ed.

42.11.08.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.08Montgomeryite groupGroup
  • 42.11.08.03CalcioferriteSpecies
CIM

19.14.16

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.16CalcioferriteSpecies

Group, growth & confusion

In the same group
1 members
Often grow together
5 minerals

Literature, links & citation

Citations
  1. 1858Blum, J.R. (1858): Calcioferrit, eine neue Mineral-Spezies. Neues Jahrbuch für Mineralogie, Geognosie, Geologie und Petrefacten-Kunde, 258 (in German).
  2. 1868Dana, James D., Brush, George Jarvis (1868) A System of Mineralogy (5th ed.). p.882
  3. 1875Rammelsberg, Carl Friedrich (1875) Handbuch der Mineralchemie (2nd ed.) Wilhelm Engelmann, Leipzig.
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calcioferrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calcioferrite-832},
  note      = {Accessed 2026-05-11}
}