Cacoxenite

Fe3+24AlO6(PO4)17(OH)12 · 75H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cac
Discovered
1825
Also known as
  • Cacoxene
  • Cacoxeniet
  • Cacoxenit
  • +1 more

History

The name cacoxenite is a complaint dressed up in Greek. It joins kakós, meaning bad, with xénos, meaning guest. The bad guest in question is phosphorus.

Cacoxenite forms inside iron ores as a hydrated iron phosphate. When smelters charged those ores into the furnace, the phosphorus carried over into the metal and made it brittle. That was a serious flaw in nineteenth-century iron, and the mineral was named for the unwanted lodger it brought along.

The species was first documented in 1825, at an iron mine at Hrbek in Bohemia. The locality lies in the historical region that today forms the western half of the Czech Republic. That mine remains the type site of the species.

Early descriptions also noted the crystals themselves. They grow as fine needles — acicular, in mineralogical terms — fanning out from a central point in radial or star-shaped sprays. The colour ranges from golden yellow to brownish yellow.

Industrial & practical applications

Cacoxenite has no recorded industrial application. It is sought almost exclusively by collectors and museums, who prize its golden-yellow to brownish-yellow needles arranged in fine radial sprays. Specimens are valued for their colour and the geometry of their crystal tufts, not for any extractable material.

Where it forms, where it's found

Geological setting

Common accessory mineral in oxidation zone of magnetic and limonite iron ores, novaculites, rarely in iron rich sediments and soils.

Type locality
Hrbek Mine
  1. Svatá Dobrotivá (St Benigna)
  2. Zaječov
  3. Beroun District
  4. Central Bohemian Region
  5. Czech Republic

49.7595°, 13.8351°

278recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellow to brownish yellow · reddish orange · golden yellow · deep orange · green

Yellow in transmitted light.

Density
2.2 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.575 – 1.656
Surface relief
Moderate
Principal indices
nω 1.575 – 1.585 · nε 1.635 – 1.656
Pleochroism
Visible

O = Pale yellow E = Canary yellow to yellow orange

Michel-Lévy diagramhighlighted lineδ = 0.0655
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]655 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation655 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#108
Cell parameters
a = 27.559(1) Å · c = 10.55 Å
Z
2
Morphology

Crystals crudely hexagonal, acicular [0001], with a hexagonal cross section at times and indistinct pyramidal faces. Commonly in compact, concentric, spherical to radial aggregates. In bundles, randomly fibrous; as coatings or intergranular cement.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen16115.9992575.839
55.60%
26FeIronIron2455.8451340.280
28.93%
15PPhosphorusPhosphorus1730.974526.558
11.37%
1HHydrogenHydrogen1621.008163.296
3.52%
13AlAluminiumAluminium126.98226.982
0.58%
Total4632.955100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al

Synonyms

  • Cacoxene
  • Cacoxeniet
  • Cacoxenit
  • Cacoxeno

In other languages

French
Cacoxène · Cacoxénite · Kacoxène
German
Kakoxen
Spanish
Cacoxenita
Italian
Cacoxenite
Japanese
カコクセナイト · カコクセン石

Classification

Strunz
10th ed.

8.DC.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.40CacoxeniteSpecies
Dana
8th ed.

42.13.05.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.13MiscellaneousType
  • 42.13.05— unnamed intermediate level —Group
  • 42.13.05.01CacoxeniteSpecies
CIM

19.14.27

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.27CacoxeniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1825Steinmann (1825) Vortr. Böhm. Ges., Prague (as Kakoxen).
  2. 1826Steinmann, J. (1826) 47. Kakoxen. Handbuch der Oryktognosie, 2, 749-750.
  3. 1826Steinmann, J. (1826) Kákoxèn. Archiv für die Gesammte Naturlehre, 8, 446-446.
  4. 1854von Hauer (1854) Neues Jahrbuch für Mineralogie, Geologie und Paleontologie, Heidelberg, Stuttgart: 191.
  5. 1854von Hauer, K.R. (1854) Ueber die Zusammensetzung einiger Mineralien mit besonderer Rucksicht auf ihren Wasser-Gehalt. Neues Jahrbuch für Mineralogie, Geognosie, Geologie und Petrefaktenkunde, 686-701 (690-693).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cacoxenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cacoxenite-840},
  note      = {Accessed 2026-05-11}
}