Campigliaite

Cu4Mn2+(SO4)2(OH)6 · 4H2O
IMA status
  • Approved
IMA symbol
Cpg
Discovered
1981
IMA approved
1981
Also known as
  • Campigliaiet
  • IMA1981-001

Where it forms, where it's found

Geological setting

Altered skarn deposit.

Type locality
Temperino Mine
  1. Campiglia Marittima
  2. Livorno Province
  3. Tuscany
  4. Italy

43.0742°, 10.6175°

5recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Vitreous
Transparency
Transparent
Colour
Light blue
Cleavage
Perfect

(100)

Density
3.0 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 52° · 2V calc = 50°
Refractive index
1.589 – 1.659
Surface relief
Moderate
Principal indices
nα 1.589 · nβ 1.645 · nγ 1.659
Dispersion
r > v weak
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2
Cell parameters
a = 21.725(8) Å · b = 6.118(6) Å · c = 11.233(7) Å
Cell angles
β = 100.3(5) °
Ratio a:b:c
1 : 0.282 : 0.517
Unit cell volume
1464.5 ų
Z
4
Twinning

Polysynthetic, with (100) as twin plane, ubiquitous

Type-locality form

Light blue tufts.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1815.999287.982
42.64%
29CuCopperCopper463.546254.184
37.64%
16SSulfurSulfur232.06064.120
9.49%
25MnManganeseManganese154.93854.938
8.14%
1HHydrogenHydrogen141.00814.112
2.09%
Total675.336100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Campigliaiet
  • IMA1981-001

In other languages

French
Campigliaïte
German
Campigliait · IMA 1981-001
Italian
Campigliaite

Classification

Strunz
10th ed.

7.DD.30

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.30CampigliaiteSpecies
Dana
8th ed.

31.06.06.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.06(AB)5(XO4)2Zq·xH2OType
  • 31.06.06— unnamed intermediate level —Group
  • 31.06.06.01CampigliaiteSpecies
CIM

25.2.22

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.22CampigliaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1982Menchetti, S., Sabelli, C. (1982) Campigliaite, Cu4Mn(SO4)2(OH)6·4H2O, a new mineral from Campiglia Marittima, Tuscany, Italy. American Mineralogist, 67 (3-4) 385-393
  2. 2005(2005) Campigliaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Campigliaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/campigliaite-876},
  note      = {Accessed 2026-05-11}
}