Serpierite

Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Spe
Discovered
1881
Also known as
  • Serpieriet

Where it forms, where it's found

Geological setting

secondary mineral in the oxidized zone of hydrothermal Cu–Zn-bearing hydrothermal mineral deposits

Type locality
Kamariza mines (Kamareza mines)
  1. Agios Konstantinos (Kamariza)
  2. Lavreotiki
  3. East Attica
  4. Attica
  5. Greece
313recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · pearly on cleavage surfaces.
Transparency
Transparent
Colour
Dark sky-blue ("linarite-blue") to medium sky-blue · greenish blue in transmitted light.
Streak
White or pale blue
Tenacity
brittle
Cleavage
Perfect

Perfect on (001).

Fracture
Splintery
Density
3.07 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 33 – 37° · 2V calc = 37°
Refractive index
1.584 – 1.647
Surface relief
Moderate
Principal indices
nα 1.584 · nβ 1.642 · nγ 1.647
Birefringence
0.063
Pleochroism
Visible

X = c = Nearly colourless Y = a = Deep greenish blue Z = b = Deep greenish blue

Dispersion
small
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0630
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]630 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation630 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 22.186(2) Å · b = 6.250(2) Å · c = 21.853(2) Å
Cell angles
β = 113.36(1) °
Ratio a:b:c
1 : 0.282 : 0.985
Z
8
Morphology

Typically occurs as clusters or sprays of lath-like to acicular micro-crystals, elongated on [100] and flattened on (001); more rarely botryoidal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
30.09%
30ZnZincZinc465.380261.520
28.93%
29CuCopperCopper463.546254.184
28.12%
16SSulfurSulfur232.06064.120
7.09%
20CaCalciumCalcium140.07840.078
4.43%
1HHydrogenHydrogen121.00812.096
1.34%
Total903.981100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Serpieriet

In other languages

German
Serpierit
Spanish
serpierita
Italian
serpierite

Classification

Strunz
10th ed.

7.DD.30

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.30SerpieriteSpecies
Dana
8th ed.

31.06.02.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.06(AB)5(XO4)2Zq·xH2OType
  • 31.06.02— unnamed intermediate level —Group
  • 31.06.02.01SerpieriteSpecies
CIM

25.5.7

  • 25SulphatesClass
  • 25.5Sulphates of Zn and HgGroup
  • 25.5.7SerpieriteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1881Bertrand, Emile (1881) Étude optique de différents minéraux. Bulletin de Minéralogie, 4 (4) 87-89 doi:10.3406/bulmi.1881.1635DOI: 10.3406/bulmi.1881.1635
  2. 1881Des Cloizeaux, Alfred (1881) Étude de différents minéraux. Bulletin de Minéralogie, 4 (4) 89-96 doi:10.3406/bulmi.1881.1636DOI: 10.3406/bulmi.1881.1636
  3. 1881Bertrand, Émile (1881) Sur un nouveau minéral du Laurium. Bulletin de Minéralogie, 4 (5). 135-136 doi:10.3406/bulmi.1881.1642 DOI: 10.3406/bulmi.1881.1642
  4. 1895Frenzel, A. (1895): Mineralogisches. Tschermaks Mineralogische und Petrographische Mitteilungen 14, 121-130 (in German). (Serpierite pp. 121-122)
  5. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Serpierite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/serpierite-3625},
  note      = {Accessed 2026-05-11}
}