Devilline

CaCu4(SO4)2(OH)6 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dev
Discovered
1864
Also known as
  • Devillit
  • Devillite
  • Herrengrundit
  • +5 more

Where it forms, where it's found

Geological setting

In the oxidation zone of copper deposits.

Type locality
Cornwall
  1. England
  2. UK
396recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · pearly
Transparency
Transparent
Colour
Green · bluish-green · green in transmitted light.
Streak
Light green
Tenacity
brittle
Cleavage
Perfect

On (001) perfect. On (110) and (101), or (101), distinct.

Density
3.084 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 37 – 41° · 2V calc = 42°
Refractive index
1.585 – 1.66
Surface relief
Moderate
Principal indices
nα 1.585 – 1.586 · nβ 1.649 – 1.651 · nγ 1.660
Birefringence
0.075
Pleochroism
Visible

X ~ c = Very light green Y = Green Z = b = Turquoise-green

Dispersion
small
Michel-Lévy diagramhighlighted lineδ = 0.0750
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]750 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation750 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 20.867 Å · b = 6.135 Å · c = 22.187 Å
Cell angles
β = 102.73 °
Ratio a:b:c
1 : 0.294 : 1.063
Z
8
Morphology

As thin, six-sided plates flattened (001) and striated [010]. Commonly as interlaced crusts or as rosettes of plate- or lath-like crystals.

Twinning

On (010)

Type-locality form

A think crust of microscopic lamellar crystals, covered by langite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
42.34%
29CuCopperCopper463.546254.184
39.56%
16SSulfurSulfur232.06064.120
9.98%
20CaCalciumCalcium140.07840.078
6.24%
1HHydrogenHydrogen121.00812.096
1.88%
Total642.461100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Devillit
  • Devillite
  • Herrengrundit
  • Herrengrundite
  • Lyellit
  • Lyellite
  • Urvölgyit
  • Urvölgyite

In other languages

French
Devilline
German
Devillin · Devillit · Herrengrundit · Lyellit · Urvölgyit
Spanish
Devillina
Italian
Devillina
Chinese
钙铜矾

Classification

Strunz
10th ed.

7.DD.30

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.30DevillineSpecies
Dana
8th ed.

31.06.01.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.06(AB)5(XO4)2Zq·xH2OType
  • 31.06.01— unnamed intermediate level —Group
  • 31.06.01.01DevillineSpecies
CIM

25.2.17

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.17DevillineSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1864Maskelyne (1864) Chemical News and Journal of Industrial Science, London: 10: 263 (as Lyellite).
  2. 1864Pisani, F. (1864) Sur une nouvelle espèce minérale du Cornouailles, la devilline. Comptes Rendus Hebdomadaires des Séances de l'Académie des Sciences: 59: 813-814.
  3. 1865Church, A. H. (1865) On some hydrated cupric oxysulphates from Cornwall. Journal of the Chemical Society, 18. 83-88 doi:10.1039/js8651800083DOI: 10.1039/js8651800083
  4. 1879Aristides, Brezina (1879) Herrengrundit, ein neues basisches Kupfersulfat. Zeitschrift für Kristallographie und Mineralogie, 3 (1). 359-380 doi:10.1524/zkri.1879.3.1.359DOI: 10.1524/zkri.1879.3.1.359
  5. 1879Szabó (1879) Mineralogische und petrographische Mitteilungen, Vienna: 2: 311 (as Urvölgyite).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Devilline — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/devilline-1270},
  note      = {Accessed 2026-05-11}
}