Orthoserpierite

CaCu4(SO4)2(OH)6 · 3H2O
IMA status
  • Approved
IMA symbol
Ospe
Discovered
1985
Also known as
  • IMA1983-022a
  • Orthoserpieriet
  • Orthoserpierita

Where it forms, where it's found

Type locality
Chessy copper mines
  1. Chessy
  2. Villefranche-sur-Saône
  3. Rhône
  4. Auvergne-Rhône-Alpes
  5. France

45.8958°, 4.6128°

43recorded occurrences
Source · OpenStreetMap

Physical

Colour
Sky-blue
Streak
Light green
Fracture
Splintery
Density
3.00 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 32° · 2V calc = 32°
Refractive index
1.586 – 1.65
Surface relief
Moderate
Principal indices
nα 1.586 · nβ 1.645 · nγ 1.65
Pleochroism
Weak

X = colorless to very pale green, Y = Z = pale green.

Dispersion
Distinct, r>v
Extinction
X = c, Y = a, Z = b
UV response
Mauve fluorescence in LW or SW.
Michel-Lévy diagramhighlighted lineδ = 0.0640
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]640 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation640 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#29
Cell parameters
a = 22.10(2) Å · b = 6.20(2) Å · c = 20.39(2) Å
Ratio a:b:c
1 : 0.281 : 0.923
Z
8
Morphology

Tabular crystals, flattened on (001) and elongated parallel to the b-axis.

Type-locality form

Masses and fibrous crusts of sky-blue crystals to 0.2 mm.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
42.34%
29CuCopperCopper463.546254.184
39.56%
16SSulfurSulfur232.06064.120
9.98%
20CaCalciumCalcium140.07840.078
6.24%
1HHydrogenHydrogen121.00812.096
1.88%
Total642.461100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1983-022a
  • Orthoserpieriet
  • Orthoserpierita

In other languages

German
IMA 1983-022a · Orthoserpierit
Italian
Orthoserpierite · Ortoserpierite

Classification

Strunz
10th ed.

7.DD.30

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.30OrthoserpieriteSpecies
Dana
8th ed.

31.06.07.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.06(AB)5(XO4)2Zq·xH2OType
  • 31.06.07— unnamed intermediate level —Group
  • 31.06.07.01OrthoserpieriteSpecies
CIM

25.5.8

  • 25SulphatesClass
  • 25.5Sulphates of Zn and HgGroup
  • 25.5.8OrthoserpieriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1985Sarp, H. (1985) Orthoserpiérite Ca(CuZn)4(SO4)2(OH)6·3H2O, un nouveau minéral de la Mine de Chessy, France, polymorphe de la serpiérite. Schweizerische Mineralogische und Petrographische Mitteilungen, 65, 1-7.
  2. 1987Hawthorne, Frank C., Jambor, John L., Bladh, Kenneth W., Burke, Ernst A. J., Grice, Joel D., Phillips, Don, Roberts, Andrew C., Schedler, Robert A., E., James (1987) New mineral names. American Mineralogist, 72 (9-10) 1023-1028
  3. 1989Ondruš, P., Hyršl, J. (1989) New finds and revision of secondary minerals from Příbram district. Acta Universitatis Carolinae, Geologica: 1989: 521-533. [PXRD data]
  4. 1992Krause, W., Täuber, H. (1992) Zum Kenntnisstand der Minerale Serpierit, Orthoserpierit und Devillin. Aufschluss: 43: 1-25. (in German)
  5. 2005(2005) Orthoserpierite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Orthoserpierite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/orthoserpierite-3031},
  note      = {Accessed 2026-05-11}
}