Chalcopyrite

CuFeS2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ccp
Discovered
1725
Also known as
  • Chalcopirita
  • Chalcopyrita
  • Chalkopyrita
  • +25 more

History

Chalcopyrite has been the most important ore of copper since the Bronze Age. Major historical workings include Río Tinto in Spain, the Ani mine in Japan, Butte in Montana, and Joplin in Missouri.

For centuries, the mineral was confused with pyrite. The two share the brassy lustre and the spark-when-struck behaviour that gave both their Greek name. Dioscorides, writing around 50 CE, listed them together under the umbrella term purites lithos in book 5 of his medical treatise On Medical Material.

In 1725, Johann Friedrich Henckel separated chalcopyrite from pyrite by giving it its own name. He combined the Greek chalkos (copper) with pyrites (strike fire) — the copper one that strikes fire.

Industrial & practical applications

Chalcopyrite is the principal ore of copper, the most abundant copper-bearing mineral on Earth. The world's copper supply rests on chalcopyrite mining.

Two extraction routes are in use. Pyrometallurgy — the heat route — is the commercially dominant one. The ore is crushed and ground, the mineral concentrated by froth flotation, then smelted, refined, and electro-refined into pure copper. Hydrometallurgy, the water-chemistry route, handles ores that pyrometallurgy cannot reach economically.

The smelting step produces sulfur dioxide gas, which is captured and converted into sulfuric acid — a major by-product of every modern copper smelter.

Where it forms, where it's found

Geological setting

Chalcopyrite is a prevalent sulfide mineral in ore deposits and hosts various trace elements such as Ag, Co, As, Se, Sb, Te, Bi, etc. The variations in trace element contents, as well as Fe, S, and Cu isotopic compositions of chalcopyrite are controlled by a series of factors including metallogenic temperature and pressure, fluid compositions, metal sources, and sulfide equilibrium. Chalcopyrite is found in porphyry Cu deposits (PCDs), sedimentary rock-hosted stratiform Cu deposits (SSCs), iron oxide Cu-Au deposits (IOCGs), sedimentary exhalative deposits (SEDEXs), magmatic Cu-Ni sulfide deposits (MSDs), and volcanogenic massive sulfide deposits (VMSs), etc. Different types of ore deposits show significantly distinct chalcopyrite geochemical characteristics. For example, in PCDs, chalcopyrite is notably enriched in Zn and Pb, with negative δ34S values (−2.1 ± 3.64 ‰, n = 32) due to sediment contributions. Positive δ65Cu values (1.5 ± 2.00 ‰, n = 140) indicate a mantle-crustal mixed source, while negative δ57Fe values (−4.3 ± 5.10 ‰, n = 32) likely result from Fe isotope fractionation during magnetite precipitation or continental crust contamination. In MSDs, Cr is the most enriched element, with positive δ34S values (1.0 ± 2.14 ‰, n = 185) and slightly negative δ⁶5Cu values (−0.46 ± 0.50 ‰, n = 52). Chalcopyrite in SSCs is enriched in Zn and As, characterized by negative δ34S (−3.6 ± 0.12 ‰, n = 190) and δ65Cu values (−0.59 ± 0.98 ‰, n = 118). [[1]]

28,498recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Brass yellow · often with an iridescent tarnish.
Streak
Greenish black
Tenacity
brittle
Cleavage
Poor/Indistinct

Indistinct on (011), sometimes distinct.

Fracture
Irregular/Uneven
Density
4.1 g/cm³

Optical

Pleochroism
Weak
Optical colour
Yellow against a white/gray phase, greenish-yellow when next to gold.
Anisotropism
Weak, but distinct blue-gray to yellow-green
Bireflectance
Weak
Internal reflections
None
Tropism
Anisotropic
Reflectance R%
(16.0,17.3) 400, (20.0,21.3) 420, (24.8,26.1) 440, (30.2,31.4) 460, (34.9,35.9) 480, (38.9,39.9) 500, (41.9,42.7) 520, (44.0,44.9) 540, (45.4,46.4) 560, (46.6,47.6) 580, (47.1,48.3) 600, (47.5,48.6) 620, (47.6,48.7) 640, (47.6,48.7) 660, (47.6,48.6) 680, (47.6,48.6) 700
Luminescence
None
Reflected-light panel
39.2 %anisotropic · dual curve
Specimen sRGB 244, 164, 63
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Weak
Anisotropism
Weak, but distinct blue-gray to yellow-green
Reflected colour
Yellow against a white/gray phase, greenish-yellow when next to gold.
Internal reflections
None

Crystallography

Crystal system
Tetragonal
Space group
#141
Cell parameters
a = 5.289 Å · c = 10.423 Å
Z
4
Morphology

Typically found as equant to wedge-shaped pseudo-tetrahedral disphenoidal crystals, often modified by tetragonal scalenohedral faces. Mostly found massive or in disseminated grains and major deposits of such material are known.

Twinning

Twinned on (112) and (012), penetration or cyclic.

Epitaxy

Pyrite on chalcopyrite from Ege-Khay, Yakutia, Russia (Novgorodova 1977).

Comment

Subcell: I-centred tetragonal, a = 3.74, c = 5.21 Å.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
16SSulfurSulfur232.06064.120
34.94%
29CuCopperCopper163.54663.546
34.63%
26FeIronIron155.84555.845
30.43%
Total183.511100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag
  • Au
  • In
  • Tl
  • Se
  • Te

Synonyms

  • Chalcopirita
  • Chalcopyrita
  • Chalkopyrita
  • Chalkopyrite
  • Copper Pyrite
  • Copper Pyrites
  • Cuivre Jaune
  • Cuivre Pyriteux
  • Cupropyrit
  • Cupropyrita
  • Cupropyrite
  • Gelbkupfererz
  • Gelferz
  • Kobberkis
  • Kopparglasertz
  • Kupfereisenerz
  • Kupfereisenerzkies
  • Kupferkies
  • Kupferkis
  • Pirita de Cobre
  • Pyrites of Copper
  • Rame giallo
  • Towanit
  • Towanita
  • Towanite
  • Yellow Copper
  • Yellow Copper Ore
  • Yellow Pyrite

In other languages

French
Blister Copper · chalcopyrite · Chalkopyrite · CuFeS2 · Cuivre jaune · Cuivre pyriteux · Mine de cuivre jaune · pyrite cuivreuse · Towanite
German
Buntkupfer · Chalkopyrit · Gelbkupfererz · Kupfereisenerz · Kupferkies
Spanish
calcopirita · calcopiritas · pirita de cobre
Italian
Calcopirite
Portuguese
calcopirita · Calcopirite · Minério de cobre
Japanese
カルコパイライト · 黄銅鉱
Chinese
黃銅礦
Simplified Chinese
黄铜矿
Traditional Chinese
黃銅礦
Russian
золотая обманка · медный колчедан · халькопирит
Arabic
كالكوبيريت

Classification

Strunz
10th ed.

2.CB.10a

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CBWith Zn, Fe, Cu, Ag, etc.Group
  • 2.CB.10aChalcopyriteSpecies
Dana
8th ed.

02.09.01.01

  • 02SulfidesClass
  • 02.09AmBnXp, with (m+n):p = 1:1Type
  • 02.09.01Chalcopyrite Group (Tetragonal: I-42d)Group
  • 02.09.01.01ChalcopyriteSpecies
CIM

3.1.25

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.1Sulphides etc. of CuGroup
  • 3.1.25ChalcopyriteSpecies

Group, growth & confusion

In the same group
6 members
Often grow together
63 minerals

Literature, links & citation

Citations
  1. 1725Henckel, J.F. (1725) Pyritologia, oder Kieß Historie. Verlegts Johann Christian Martini (Leipzig), pages 114-115. [Chalcopyrites (Latin), Kupfer-Kieß (German)].
  2. 1934Buerger, N. W., Buerger, M. J. (1934) Crystallographic relations between cubanite segregation plates, chalcopyrite matrix, and secondary chalcopyrite twins. American Mineralogist, 19 (7) 289-303
  3. 1934Buerger, N. W. (1934) The unmixing of chalcopyrite from sphalerite. American Mineralogist, 19 (11) 525-530
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1966YUND, R. A.; KULLERUD, G. (1966) Thermal Stability of Assemblages in the Cu-Fe-S System. Journal of Petrology, 7 (3). 454-488 doi:10.1093/petrology/7.3.454DOI: 10.1093/petrology/7.3.454
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalcopyrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalcopyrite-955},
  note      = {Accessed 2026-05-11}
}