Flörkeite

(K3Ca2Na)[Al8Si8O32] · 12H2O
IMA status
  • Approved
IMA symbol
Flö
IMA approved
2008
Also known as
  • Flörkeiet
  • IMA2008-036
  • Unnamed (Triclinic "phillipsite")

Where it forms, where it's found

Geological setting

A pyrometamorphically modified Ca-rich xenolith of the Tertiary basement, which was enclosed with the leucite-tephritic lava.

Type locality
Caspar quarry
  1. Ettringen
  2. Vordereifel
  3. Mayen-Koblenz
  4. Rhineland-Palatinate
  5. Germany

50.3525°, 7.2335°

10recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

Indistinct cleavage on (001).

Fracture
Irregular/Uneven
Density
2.270 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 71.0° · 2V calc = 70.2°
Refractive index
1.506 – 1.518
Surface relief
Moderate
Principal indices
nα 1.506 · nβ 1.514 · nγ 1.518
Pleochroism
Non-pleochroic
Dispersion
weak (r < v)
UV response
none
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 19.965 Å · b = 14.271 Å · c = 8.704 Å
Cell angles
α = 88.37 ° · β = 125.08 ° · γ = 89.57 °
Ratio a:b:c
1 : 0.715 : 0.436
Z
2
Parting
None
Type-locality form

Subparallel, short prismatic, pseudo-monoclinic crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4415.999703.956
50.68%
14SiSiliconSilicon828.085224.680
16.17%
13AlAluminiumAluminium826.982215.856
15.54%
19KPotassiumPotassium339.098117.294
8.44%
20CaCalciumCalcium240.07880.156
5.77%
1HHydrogenHydrogen241.00824.192
1.74%
11NaSodiumSodium122.99022.990
1.66%
Total1389.124100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Flörkeiet
  • IMA2008-036
  • Unnamed (Triclinic "phillipsite")

In other languages

German
Flörkeit · IMA 2008-036
Italian
flörkeite · IMA2008-036

Classification

Strunz
10th ed.

9.GC.10

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GCChains of doubly-connected 4-membered ringsGroup
  • 9.GC.10FlörkeiteSpecies
Dana
8th ed.

77.01.10.05

  • 77Tectosilicates ZeolitesClass
  • 77.01Zeolite group - True zeolitesType
  • 77.01.10— unnamed intermediate level —Group
  • 77.01.10.05FlörkeiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2005Kolitsch, U., Blaß, G. (2005) Triclinic "Phillipsite" in a Ca-rich xenolith from the Bellerberg, Eifel, Germany: Reduction of symmetry due to nearly complete Al-Si-disordering - evidence for an unusual cooling history? Mitteilungen der Österreichischen Mineralogischen Gesellschaft: 151: 66. https://opac.geologie.ac.at/ais312/dokumente/OEMG_Band_151_2005.pdf
  2. 2008Lengauer, C.; Kolitsch, U.; Tillmanns, E. (2008): More data on (Na,K,Ca)6[Al8Si8O32]•12H2O, a new triclinic phillipsite-type zeolite from the Bellerberg volcano, Eifel, Germany. Annual Meeting of the DMG, Berlin, Germany, September 14-17, 2008; CD with abstracts, Abs. no. 348.
  3. 2009Blass, G., Graf, H.-W., Kolitsch, U., Sebold, D. (2009): Die Neufunde aus der Vulkaneifel (II) [The new finds from the volcanic Eifel (II)]. Mineralien-Welt 20 (2), 38-49.
  4. 2009Lengauer, Christian L., Kolitsch, Uwe, Tillmanns, Ekkehart (2009) Flörkeite, K3Ca2Na[Al8Si8O32]·12H2O, a new phillipsite-type zeolite from the Bellerberg, East Eifel volcanic area, Germany. European Journal of Mineralogy, 21 (4). 901-913 doi:10.1127/0935-1221/2009/0021-1952 DOI: 10.1127/0935-1221/2009/0021-1952
  5. 2010Ternes, B. (2010): Flörkeit - ein neuer Zeolith und seine Begleiter am Bellerberg-Vulkan. Lapis, 35 (10), 28-29 (in German).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Flörkeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/florkeite-38900},
  note      = {Accessed 2026-05-11}
}