Bikitaite

LiAlSi2O6 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bik
Discovered
1957
Also known as
  • Bikitaiet

Where it forms, where it's found

Geological setting

Granite pegmatite

Granite pegmatite

Type locality
Nolan property
  1. Bikita District
  2. Masvingo
  3. Zimbabwe

-19.9504°, 31.4395°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless · White
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on the (100), Good on the (001)

Fracture
Conchoidal
Density
2.28 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 45°
Refractive index
1.51 – 1.523
Surface relief
Moderate
Principal indices
nα 1.510 · nβ 1.521 · nγ 1.523
Birefringence
0.013
Pleochroism
Non-pleochroic
Dispersion
r<v
Extinction
X^c = 28°, Z=b
UV response
Not fluorescent in UV, but may be associated with red-fluorescing eucryptite
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 8.606 Å · b = 4.9573 Å · c = 7.597 Å
Cell angles
α = 89.89 ° · β = 114.42 ° · γ = 89.96 °
Ratio a:b:c
1 : 0.576 : 0.883
Unit cell volume
295.11 ų
Z
1
Morphology

Granular; bladed crystals are rare

Type-locality form

colorless glassy grains

Comment

Originally determined as monoclinic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
54.87%
14SiSiliconSilicon228.08556.170
27.52%
13AlAluminiumAluminium126.98226.982
13.22%
3LiLithiumLithium16.9406.940
3.40%
1HHydrogenHydrogen21.0082.016
0.99%
Total204.101100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bikitaiet

In other languages

German
Bikitait
Italian
bikitaite

Classification

Strunz
10th ed.

9.GD.55

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GDChains of 6-membered rings – tabular zeolitesGroup
  • 9.GD.55BikitaiteSpecies
Dana
8th ed.

77.02.01.01

  • 77Tectosilicates ZeolitesClass
  • 77.02Zeolite group - related speciesType
  • 77.02.01— unnamed intermediate level —Group
  • 77.02.01.01BikitaiteSpecies
CIM

16.1.6

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.1Aluminosilicates of LiGroup
  • 16.1.6BikitaiteSpecies

Group, growth & confusion

Often grow together
3 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1957Hurlbut, Cornelius S. (1957) Bikitaite, LiAlSi2O6·H2O, a new mineral from Southern Rhodesia. American Mineralogist, 42 (11-12) 792-797
  2. 1958Hurlbut, C. S. Jr. (1958) Additional data on bikitaite. American Mineralogist, 43 (7-8) 768-770
  3. 1968Leavens, Peter B., Hurlbut, C. S., Nelen, and Joseph A. (1968) Eucryptite and bikitaite from King's Mountain, North Carolina. American Mineralogist, 53 (7-8) 1202-1207
  4. 1974Kocman, Vladimir, Gait, Robert I., Rucklidge, and John (1974) The crystal structure of bikitaite, Li[AlSi2O6]·H2O. American Mineralogist, 59 (1-2) 71-78
  5. 1984Annehed, Håkan, Fälth, Lars (1984) The crystal structure of Cs0.35Al0.35Si2.65O6, a cesium-aluminosilicate with the bikitaite framework. Zeitschrift für Kristallographie - Crystalline Materials, 166 (3-4). 301-306 doi:10.1524/zkri.1984.166.3-4.301DOI: 10.1524/zkri.1984.166.3-4.301
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bikitaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bikitaite-670},
  note      = {Accessed 2026-05-11}
}