Chiavennite

CaMn2+(BeOH)2Si5O13 · 2H2O
IMA status
  • Approved
IMA symbol
Cve
Discovered
1970
Also known as
  • Chiavenniet
  • IMA1981-038

Where it forms, where it's found

Geological setting

Alpine pegmatites (25-27 m.y.).

Alkaline syenite pegmatites and granite pegmatites

Type locality
Tanno Pegmatitic Field
  1. Chiavenna
  2. Sondrio Province
  3. Lombardy
  4. Italy

46.3145°, 9.4046°

28recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pale orange-yellow
Streak
White; pale ocher
Cleavage
Perfect

Good to perfect cleavages along (100), (010), and (001).

Density
2.64 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50° · 2V calc = 52°
Refractive index
1.596 – 1.618
Surface relief
Moderate
Principal indices
nα 1.596 · nβ 1.600 · nγ 1.618
Pleochroism
Visible

X = colorless to pale yellow; Z = yellow-orange.

Dispersion
r < v weak
Extinction
X = a, Y = b, Z = c.
Michel-Lévy diagramhighlighted lineδ = 0.0220
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]220 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation220 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 8.7466(3) Å · b = 4.8972(3) Å · c = 31.3160(16) Å
Cell angles
β = 90.128(4) °
Ratio a:b:c
1 : 0.560 : 3.580
Unit cell volume
1341.39 ų
Morphology

Crystals from the TL are showing a flat pseudohexagonal habit. From Larvik Plutonic Complex (Langesundsfjorden area), Norway: Spherulitic aggregates concisting of spear-shaped crystals, flattened on (010), terminated by the orthorhombic pyramid (161).

Twinning

Common, on (100).

Type-locality form

As euhedral orange grains and as crusts coating beryl.

Comment

Previously reported to be orthorhombic; unit cell parameters for the orthorhombic dehydrated phase, i.e., at 425oC, of the Pbcn cell, transformed in (non-standard) Pnca setting: a=8.6795(15), b=4.9017(10), c=31.513(6).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
51.17%
14SiSiliconSilicon528.085140.425
26.42%
25MnManganeseManganese154.93854.938
10.34%
20CaCalciumCalcium140.07840.078
7.54%
4BeBerylliumBeryllium29.01218.024
3.39%
1HHydrogenHydrogen61.0086.048
1.14%
Total531.496100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Fe
  • Mg
  • Ca
  • Na
  • K
  • F
  • C

Synonyms

  • Chiavenniet
  • IMA1981-038

In other languages

German
Chiavennit · IMA 1981-038
Italian
chiavennite · IMA1981-038

Classification

Strunz
10th ed.

9.GF.25

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GFOther Rare ZeolitesGroup
  • 9.GF.25ChiavenniteSpecies
Dana
8th ed.

70.05.01.01

  • 70Inosilicates Column or Tube StructuresClass
  • 70.05Column or Tube Structures with chains linked by BeType
  • 70.05.01— unnamed intermediate level —Group
  • 70.05.01.01ChiavenniteSpecies
CIM

14.3.18

  • 14Silicates not Containing AluminumClass
  • 14.3Silicates of BeGroup
  • 14.3.18ChiavenniteSpecies

Group, growth & confusion

Often grow together
7 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1983Bondi, Mirella, Griffin, William L., Mattioli, Vittorio, Mottana, Annibale (1983) Chiavennite, CaMnBe2Si5O13(OH)2·2H2O, a new mineral from Chiavenna (Italy) American Mineralogist, 68 (5-6) 623-627
  2. 1983Raade, Gunnar, Åmli, Reidar, Mladeck, Micael H., Din, Victor K., Larsen, Alf Olav, Åsheim, Arne (1983) Chiavennite from syenite pegmatites in the Oslo Region, Norway. American Mineralogist, 68 (5-6) 628-633
  3. 1995Tazzoli, Vittorio, Domeneghetti, M . Chiara, Mazzi, Fiοrenzο, Cannillo, Eliο (1995) The crystal structure of chiavennite. European Journal of Mineralogy, 7 (6) 1339-1344 doi:10.1127/ejm/7/6/1339DOI: 10.1127/ejm/7/6/1339
  4. 1997Coombs, Douglas S., Alberti, Alberto, Armbruster, Thomas, Artioli, Gilberto, Colella, Carmine, Galli, Ermanno, Grice, Joel D., Liebau, Friedrich, Mandarino, Joseph A., Minato, Hideo, et al. (1997) Recommended nomenclature for zeolite minerals; report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. The Canadian Mineralogist, 35 (6). 1571-1606
  5. 2000Langhof, Jörgen, Holtstam, Dan, Gustafsson, Lars (2000) Chiavennite and zoned genthelvite-helvite as late-stage minerals of the Proterozoic LCT pegmatites at Utö, Stockholm, Sweden. GFF, 122 (2). 207-212 doi:10.1080/11035890001222207 DOI: 10.1080/11035890001222207
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chiavennite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chiavennite-1002},
  note      = {Accessed 2026-05-11}
}