Fluorophlogopite

KMg3(Si3Al)O10F2
IMA status
  • Approved
IMA symbol
Fphl
IMA approved
2006
Also known as
  • Fluorophlogopiet
  • Fluorphlogopit
  • Fluorphlogopite
  • +2 more

Where it forms, where it's found

Geological setting

Locally metasomatized benmoreitic autoclastic lavas.

Type locality
Mt Calvario
  1. Biancavilla
  2. Metropolitan City of Catania
  3. Sicily
  4. Italy

37.6411°, 14.8758°

78recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale yellow
Tenacity
brittle
Cleavage
Perfect

on (001)

Brittle to malleable

Fracture
Micaceous
Density
2.83 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 17°
Refractive index
1.543 – 1.5688
Surface relief
Moderate
Principal indices
nα 1.543 · nβ 1.5682 · nγ 1.5688
Pleochroism
Non-pleochroic
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0258
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]258 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation258 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.3094(4) Å · b = 9.1933(7) Å · c = 10.1437(4) Å
Cell angles
β = 100.062(3) °
Ratio a:b:c
1 : 1.732 : 1.911
Z
2
Morphology

Thin lamella

Type-locality form

Very thin, flat laminae with a diameter of 200–400 µm.

Comment

1M polytype

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
37.98%
14SiSiliconSilicon328.08584.255
20.00%
12MgMagnesiumMagnesium324.30572.915
17.31%
19KPotassiumPotassium139.09839.098
9.28%
9FFluorineFluorine218.99837.996
9.02%
13AlAluminiumAluminium126.98226.982
6.41%
Total421.236100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Fluorophlogopiet
  • Fluorphlogopit
  • Fluorphlogopite
  • fluorphologopite
  • IMA2006-011

In other languages

French
fluorophlogopite
German
Fluorophlogopit · IMA 2006-011
Italian
fluoroflogopite
Japanese
フルオロフロゴパイト

Classification

Strunz
10th ed.

9.EC.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.20FluorophlogopiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1954Yoder, H.S., Eugster, H.P. (1954) Phlogopite synthesis and stability range. Geochimica et Cosmochimica Acta, 6 (4) 157-185 doi:10.1016/0016-7037(54)90049-6DOI: 10.1016/0016-7037(54)90049-6
  2. 1955Kohn, J. A., Hatch, R. A. (1955) Synthetic mica investigations, VI: X-ray and optical data on synthetic fluor-phlogopite. American Mineralogist, 40 (1-2) 10-21
  3. 1973McCauley, James W., Newnham, R. E., Gibbs, and G. V. (1973) Crystal structure analysis of synthetic fluorophlogopite. American Mineralogist, 58 (3-4) 249-254
  4. 1982Peterson, E.U., Essene, E.J., Peacor, D.R., Valley, J.W. (1982) Fluorine end-member micas and amphiboles. American Mineralogist: 67(5-6): 538-544.
  5. 1982Valley, J.W., Petersen, E.U., Essene, E.J., Bowman, J.R. (1982) Fluorphlogopite and fluortremolite in Adirondack marbles and calculated C–O–H–F fluid compositions. American Mineralogist: 67: 545-557.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fluorophlogopite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fluorophlogopite-29139},
  note      = {Accessed 2026-05-11}
}