Oxyphlogopite

K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2
IMA status
  • Approved
IMA symbol
Ophl
IMA approved
2009
Also known as
  • IMA2009-069
  • Oxyphlogopiet
  • Titanbiotit (of Freudenberg)
  • +1 more

Where it forms, where it's found

Geological setting

Oxyphlogopite is pneumatolitic in origin. It occurs as crystals lining the walls of cavities in cavernous alkali basalt and growing into the rock near the caverns.

Type locality
Rothenberg Quarry
  1. Bell
  2. Mendig
  3. Mayen-Koblenz
  4. Rhineland-Palatinate
  5. Germany

50.4044°, 7.2322°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Dark brown to almost black
Streak
Brown
Tenacity
flexible
Cleavage
Perfect

on (001)

Density
3.06 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 17°
Refractive index
1.625 – 1.669
Surface relief
Moderate
Principal indices
nα 1.625 · nβ 1.668 · nγ 1.669
Pleochroism
Visible

Brown to dark brown

Dispersion
r < v, strong
Michel-Lévy diagramhighlighted lineδ = 0.0440
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]440 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation440 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.3165(1) Å · b = 9.2000(2) Å · c = 10.0602(2) Å
Cell angles
β = 100.354(2) °
Ratio a:b:c
1 : 1.730 : 1.892
Z
2
Type-locality form

Imperfect prismatic and thin lamellar crystals.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
21.98%
26FeIronIron355.845167.535
19.18%
22TiTitaniumTitanium347.867143.601
16.44%
14SiSiliconSilicon428.085112.340
12.86%
13AlAluminiumAluminium426.982107.928
12.36%
12MgMagnesiumMagnesium324.30572.915
8.35%
19KPotassiumPotassium139.09839.098
4.48%
9FFluorineFluorine218.99837.996
4.35%
Total873.401100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Na

Synonyms

  • IMA2009-069
  • Oxyphlogopiet
  • Titanbiotit (of Freudenberg)
  • Wodanit

In other languages

German
IMA 2009-069 · Oxyphlogopit
Italian
oxyphlogopite

Classification

Strunz
10th ed.

9.EC.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.20OxyphlogopiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2010Chukanov N.V., Mukhanova, A.A., Rastsvetaeva, R.K., Belakovskiy, D.I., Möckel, S., Karimova, O.V., Britvin, S.N. & Krivovichev, S.V. (2010): Oxyphlogopite, K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2, a new mica-group mineral. Zapiski Rossiyskogo Mineralogicheskogo Obshchestva, 139(3), 31-40 (in Russian). English translation: (2011) Geology of Ore Deposits, 53, 583-590.
  2. 2011Chukanov, N. V., Mukhanova, A. A., Rastsvetaeva, R. K., Belakovsky, D. I., Möckel, S., Karimova, O. V., Britvin, S. N., Krivovichev, S. V. (2011) Oxyphlogopite K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2: A new mineral species of the mica group. Geology of Ore Deposits, 53 (7) 583-590 doi:10.1134/s1075701511070063DOI: 10.1134/s1075701511070063
  3. 2021(2021) Oxyphlogopite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Oxyphlogopite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/oxyphlogopite-39713},
  note      = {Accessed 2026-05-11}
}