Siderophyllite

KFe2+2Al(Si2Al2)O10(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Sid
Discovered
1880
Also known as
  • Hydroxyl-siderophyllite
  • Siderophylliet

Where it forms, where it's found

Type locality
Pikes Peak
  1. El Paso County
  2. Colorado
  3. USA

38.8403°, -105.0419°

105recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark green · brown · black
Cleavage
Perfect

(001)

Density
3.1 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 4°
Refractive index
1.582 – 1.625
Surface relief
Moderate
Principal indices
nα 1.582 · nβ 1.625 · nγ 1.625
Pleochroism
Weak

X = brown; Y = Z = dark brown

Dispersion
r < v moderate
Michel-Lévy diagramhighlighted lineδ = 0.0430
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]430 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation430 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 5.348(2) Å · b = 9.261(3) Å · c = 10.263(4) Å
Cell angles
β = 100.19(7) °
Ratio a:b:c
1 : 1.732 : 1.919
Z
2
Comment

Point Group: n.d.; Space Group: n.d.;1M polytype.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
39.84%
26FeIronIron255.845111.690
23.18%
13AlAluminiumAluminium326.98280.946
16.80%
14SiSiliconSilicon228.08556.170
11.65%
19KPotassiumPotassium139.09839.098
8.11%
1HHydrogenHydrogen21.0082.016
0.42%
Total481.908100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Mn
  • Mg
  • Ca
  • Li
  • Na
  • Rb
  • Cs
  • Cl
  • H2O

Synonyms

  • Hydroxyl-siderophyllite
  • Siderophylliet

In other languages

French
sidérophyllite
German
Siderophyllit
Italian
Siderofillite

Classification

Strunz
10th ed.

9.EC.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.20SiderophylliteSpecies
Dana
8th ed.

71.02.2b.05

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.02Sheets of 6-membered rings with 2:1 layersType
  • 71.02.2b— unnamed intermediate level —Group
  • 71.02.2b.05SiderophylliteSpecies
CIM

16.18.5

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.18Aluminosilicates of Fe and alkalisGroup
  • 16.18.5SiderophylliteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1881Lewis, H.C. (1881) On siderophyllite - a new mineral. Proceedings of the Academy of Natural Sciences of Philadelphia: 32: 254-255.
  2. 1944Coats, Robert R., Fahey, Joseph J. (1944) Siderophyllite from Brooks Mountain, Alaska. American Mineralogist, 29 (9-10) 373-377
  3. 1973RUTHERFORD, M. J. (1973) The Phase Relations of Aluminous Iron Biotites in the System KAlSi3O8-KAlSiO4-Al2O3-Fe-O-H. Journal of Petrology, 14 (1). 159-180 doi:10.1093/petrology/14.1.159DOI: 10.1093/petrology/14.1.159
  4. 1983Albertini, Claudio (1983) Famous Mineral Localities: Baveno, Italy. The Mineralogical Record, 14 (3) 157-168
  5. 1998Rieder, M., Cavazzini, G., D’Yakonov, Y.S., Frank-Kamenetskii, V.A., Gottardt, G., Guggenheim, S., Koval, P.V., Muller, G., Neiva, A.M.R., Radoslovich, E.W., Robert, J.L., Sassi, F.P., Takeda, H., Weiss, Z., Wones, D.R. (1998) Nomenclature of the micas. The Canadian Mineralogist, 36 (3) 905-912
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Siderophyllite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/siderophyllite-3651},
  note      = {Accessed 2026-05-11}
}