Annite

KFe2+3(AlSi3O10)(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ann
Discovered
1868
Also known as
  • Anniet
  • Annitt

Where it forms, where it's found

Geological setting

Granite

Mg-low igneous and metamorphic rocks; associated minerals at Rockport, MA, USA.

Type locality
Rockport
  1. Essex County
  2. Massachusetts
  3. USA

42.6556°, -70.6203°

382recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine · Vitreous
Transparency
Transparent · Translucent
Colour
Black · brown
Tenacity
flexible
Cleavage
Perfect

(001)

Density
3.3 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 25° · 2V calc = 12 – 36°
Refractive index
1.625 – 1.697
Surface relief
High
Principal indices
nα 1.625 – 1.631 · nβ 1.69 · nγ 1.691 – 1.697
Pleochroism

brown (X), dark brown (Y=Z)

Dispersion
weak to distinct (r < v)
Notes

Orientation: Y=b; measured 2V according to the Handbook of Mineralogy is from 0 to 5 deg.

Michel-Lévy diagramhighlighted lineδ = 0.0660
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]660 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation660 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.3860(9) Å · b = 9.3241(7) Å · c = 10.2683(9) Å
Cell angles
β = 100.63(1) °
Ratio a:b:c
1 : 1.731 : 1.906
Z
2
Morphology

Tabular crystals or cleavage fragments, both having pseudohexagonal outlines, up to 15 cm in size; foliated masses.

Twinning

Contact twins, composition surface (001), twin axis [310].

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
37.51%
26FeIronIron355.845167.535
32.73%
14SiSiliconSilicon328.08584.255
16.46%
19KPotassiumPotassium139.09839.098
7.64%
13AlAluminiumAluminium126.98226.982
5.27%
1HHydrogenHydrogen21.0082.016
0.39%
Total511.874100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Mn
  • Mg
  • Ca
  • Na
  • K
  • Cl

Synonyms

  • Anniet
  • Annitt

In other languages

French
Annite
German
Annit
Italian
Annite
Japanese
鉄雲母
Chinese
羟铁云母 · 鐵雲母 · 铁云母
Arabic
عنيت

Classification

Strunz
10th ed.

9.EC.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.20AnniteSpecies
Dana
8th ed.

71.02.2b.03

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.02Sheets of 6-membered rings with 2:1 layersType
  • 71.02.2b— unnamed intermediate level —Group
  • 71.02.2b.03AnniteSpecies
CIM

16.18.4

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.18Aluminosilicates of Fe and alkalisGroup
  • 16.18.4AnniteSpecies

Group, growth & confusion

Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. D.R. Wones, R.G. Burns, B.M. Carrol (1971): Stability and properties of synthetic annite, Am. Geophys. Union Trans. 52, 369.
  2. 1867Cooke, J.P. Jr. (1867) On cryophyllite, a new mineral species of the mica family, with some associated minerals in the granite of Rockport, Massachusetts. American Journal of Science: II(43): 217-230. (as lepidomelane)
  3. 1868Dana, James D., Brush, George Jarvis (1868) A System of Mineralogy (5th ed.). p.882
  4. 1957Yoder, Hatten S. (1957) Experimental Studies on Micas: A Synthesis. Clays and Clay Minerals, 6 (1) 42-60 doi:10.1346/ccmn.1957.0060105DOI: 10.1346/ccmn.1957.0060105
  5. 1973Hazen, Robert M., Burnham, and Charles W. (1973) The crystal structures of one-layer phlogopite and annite. American Mineralogist, 58 (9-10) 889-900
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Annite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/annite-241},
  note      = {Accessed 2026-05-11}
}