Phlogopite

KMg3(AlSi3O10)(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Phl
Discovered
1841
IMA approved
1998
Also known as
  • Bronze Mica
  • Brown Mica
  • Hydroxyl-Phlogopite
  • +4 more

History

The name phlogopite comes from the Greek phlogopós — "fire-like" or "of flaming appearance" — and points at the coppery, amber sheen of the cleavage flakes when light catches them edge-on. The early specimens were noticeably red-tinted, and that reddish cast is what the namers had in mind.

The name was coined in 1841 by the German mineralogist Johann Friedrich August Breithaupt, who singled out the magnesium-rich, iron-poor end of the dark-mica spectrum as a species in its own right. Until then, the brown and black sheet-silicates of the mica family had been lumped together under the older name biotite. Phlogopite was the pale, magnesian sibling — different enough in chemistry and origin to deserve its own label.

The boundary between phlogopite and biotite stayed fuzzy for the next century and a half. In 1998 the International Mineralogical Association settled it. Biotite, until then treated as a mineral species, was reclassified as a series name covering several end-members. Phlogopite was kept on as the magnesium end of that series. Below that line the dark micas are properly biotite-series; the name phlogopite is reserved for the magnesium pole.

Industrial & practical applications

Phlogopite is the heat-tolerant member of the mica family, and most of what industry does with it follows from that one property. The sheets stay stable to around 900 °C — well above the limit of muscovite, the more familiar transparent mica — and that ceiling defines the markets.

The largest current use is as an insulator in high-temperature electrical equipment. In the commutator of a direct-current motor or generator — the ring of copper segments that the brushes ride against to deliver current — phlogopite separates one segment from the next. It is chosen there because it wears at the same rate as the copper. A worn brush meets a flat surface rather than a stepped one. The same sheets back the resistance wire — Kanthal or Nichrome — in industrial heating elements.

Above the rolled-sheet market sits a second product: mica paper, made by pulping mica flakes and re-felting them into rolls. Phlogopite paper is rated to roughly 750–850 °C and is wrapped around the conductors of high-voltage motors, generators and transformers as their primary insulation.

Ground phlogopite is sold as a functional filler in plastics, rubber and paint. It adds heat resistance and dimensional stability to the matrix. A single mica flake is also wide enough to interrupt sound and vibration, which is why automotive interior parts often carry mica as a light-weight insulator. The same flakes turn up as extenders in coatings, where the platy shape improves barrier behaviour.

Transparent sheets of phlogopite are still cut for sight-glasses in furnaces, boilers and kerosene heaters. The mica shatters less readily than glass under steep temperature gradients.

In diamond exploration, phlogopite is one of the indicator minerals geologists sample to trace kimberlite and lamproite intrusions — the rare volcanic pipes that bring diamonds up from the deep mantle. It travels in those magmas alongside pyrope garnet, chrome diopside and ilmenite. It is a more reliable indicator in kimberlites than in lamproites, where the traditional markers thin out and phlogopite is one of the few that remain.

Where it forms, where it's found

Geological setting

Contact and regional metamorphic limestones and dolomites, ultramafic rocks.

2,595recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous - Pearly
Transparency
Transparent · Translucent
Colour
Brown · gray · green · yellow · or reddish brown
Streak
White
Tenacity
flexible
Cleavage
Perfect

on (0001)

Fracture
Micaceous
Density
2.78 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 12° · 2V calc = 16 – 20°
Refractive index
1.53 – 1.618
Surface relief
Moderate
Principal indices
nα 1.53 – 1.573 · nβ 1.557 – 1.617 · nγ 1.558 – 1.618
Pleochroism
Visible

X= yellow Y=Z= brownish red, green, yellow

Dispersion
r < v distinct
Luminescence
None
Michel-Lévy diagramhighlighted lineδ = 0.0365
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]365 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation365 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#11
Cell parameters
a = 5.3 Å · b = 9.19 Å · c = 10.15 Å
Cell angles
β = 100.08 °
Ratio a:b:c
1 : 1.734 : 1.915
Morphology

Six sided crystals, thick tabular to prismatic, commonly tapered.

Twinning

Composition plane (001), twin axis [310]

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
46.01%
14SiSiliconSilicon328.08584.255
20.19%
12MgMagnesiumMagnesium324.30572.915
17.48%
19KPotassiumPotassium139.09839.098
9.37%
13AlAluminiumAluminium126.98226.982
6.47%
1HHydrogenHydrogen21.0082.016
0.48%
Total417.254100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn
  • Ba
  • Cr
  • Na
  • Ti
  • Ni
  • Zn
  • Ca
  • Li
  • Rb
  • H2O

Synonyms

  • Bronze Mica
  • Brown Mica
  • Hydroxyl-Phlogopite
  • Magnesia Mica
  • Magnesiaglimmer
  • Magnesian Biotite
  • Rhombic Mica

In other languages

French
Mica bronzé · phlogopite
German
Phlogopit
Spanish
flogopita
Italian
Flogopite
Portuguese
flogopita · Flogopite
Japanese
金雲母
Chinese
金云母
Traditional Chinese
金雲母
Russian
флогопит
Arabic
فلوغوبيت

Classification

Strunz
10th ed.

9.EC.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.20PhlogopiteSpecies
Dana
8th ed.

71.02.2b.01

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.02Sheets of 6-membered rings with 2:1 layersType
  • 71.02.2b— unnamed intermediate level —Group
  • 71.02.2b.01PhlogopiteSpecies
CIM

16.8.6

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.8Aluminosilicates of Mg and alkalisGroup
  • 16.8.6PhlogopiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1841Breithaupt, J.F.A. (1841) Phengites Phlogopites. in Vollständige Charakteristik des Mineral-Systems 2nd Edition, Arnoldische Buchhandlung (Dresden and Leipzig), 398-399,
  2. 1954Levinson, A. A., Heinrich, E. Wm. (1954) Studies in the mica group; single crystal data on phlogopites, biotites, and manganophyllites. American Mineralogist, 39 (11-12) 937-945
  3. 1954Yoder, H.S., Eugster, H.P. (1954) Phlogopite synthesis and stability range. Geochimica et Cosmochimica Acta, 6 (4) 157-185 doi:10.1016/0016-7037(54)90049-6DOI: 10.1016/0016-7037(54)90049-6
  4. 1957Yoder, Hatten S. (1957) Experimental Studies on Micas: A Synthesis. Clays and Clay Minerals, 6 (1) 42-60 doi:10.1346/ccmn.1957.0060105DOI: 10.1346/ccmn.1957.0060105
  5. 1964Crowley, M. S., Roy, Rustum (1964) Crystalline solubility in the muscovite and phlogopite groups. American Mineralogist, 49 (3-4) 348-362
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phlogopite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phlogopite-3193},
  note      = {Accessed 2026-05-11}
}