Tetraferriannite

KFe2+3(Si3Fe3+)O10(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Tfann
Also known as
  • Ferri-annite
  • Ferriannite
  • Tetraferrianniet

Where it forms, where it's found

Geological setting

Low-grade metamorphosed banded iron formation.

Type locality
Wittenoom
  1. Ashburton Shire
  2. Western Australia
  3. Australia

-22.2360°, 118.3356°

14recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Brown to black
Streak
Light brown
Cleavage
Perfect

(001)

Optical

Optical type
Biaxial (-) · 2V measured = 10°
Refractive index
1.66 – 1.728
Surface relief
High
Principal indices
nα 1.66 · nβ 1.72 · nγ 1.728
Pleochroism
Visible

X = light reddish brown, Y = Z = pale yellow green or X = brownish red, Y = Z = pale greenish brown.

Dispersion
weak
Michel-Lévy diagramhighlighted lineδ = 0.0680
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]680 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation680 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.402(6) Å · b = 9.237(4) Å · c = 10.306(7) Å
Cell angles
β = 99.26 °
Ratio a:b:c
1 : 1.710 : 1.908
Twinning

frequent

Type-locality form

Flaky to tabular grains or as massive aggregates of fine acicular grains.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron455.845223.380
41.31%
8OOxygenOxygen1215.999191.988
35.51%
14SiSiliconSilicon328.08584.255
15.58%
19KPotassiumPotassium139.09839.098
7.23%
1HHydrogenHydrogen21.0082.016
0.37%
Total540.737100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferri-annite
  • Ferriannite
  • Tetraferrianniet

In other languages

German
Tetraferriannit
Italian
Tetra-ferri-annite · Tetraferriannite

Classification

Strunz
10th ed.

9.EC.20

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.ECPhyllosilicates with mica sheets, composed of tetrahedral and octahedral netsGroup
  • 9.EC.20TetraferrianniteSpecies
Dana
8th ed.

71.02.2b.04

  • 71Phyllosilicates Sheets of Six-membered RingsClass
  • 71.02Sheets of 6-membered rings with 2:1 layersType
  • 71.02.2b— unnamed intermediate level —Group
  • 71.02.2b.04TetraferrianniteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1963Wones, D. R. (1963) Phase equilibria of 'ferriannite', KFe3+2Fe+3Si3O10(OH)2. American Journal of Science, 261 (6). 581-596 doi:10.2475/ajs.261.6.581DOI: 10.2475/ajs.261.6.581
  2. 1964Donnay, G., Morimoto, N., Takeda, H. (1964) Trioctahedral one-layer micas. I. Crystal structure of a synthetic iron mica. Acta Crystallographica, 17 (11) 1369-1373 doi:10.1107/s0365110x64003450DOI: 10.1107/s0365110x64003450
  3. 1982Miyano, T., Miyano, S. (1982) Ferri-annite from the Dales Gorge Member iron-formations, Wittenoom area, Western Australia. American Mineralogist, 67 (11-12) 1179-1194
  4. 1998Rieder, M., Cavazzini, G., D’Yakonov, Y.S., Frank-Kamenetskii, V.A., Gottardt, G., Guggenheim, S., Koval, P.V., Muller, G., Neiva, A.M.R., Radoslovich, E.W., Robert, J.L., Sassi, F.P., Takeda, H., Weiss, Z., Wones, D.R. (1998) Nomenclature of the micas. The Canadian Mineralogist, 36 (3) 905-912
  5. 1999Rieder, M., Cavazzini, G., D’yakonov, Yu. S., Frank-Kamenetskii, V. A., Gottardi, G., Guggenheim, S., Koval’, P. V., Müller, G., Neiva, A. M. R., Radoslovich, E. W., Robert, J.-L., Sassi, F. P., Takeda, H., Weiss, Z., Wones, D. R. (1999) Nomenclature of the micas. Mineralogical Magazine, 63 (2) 267-279 doi:10.1180/minmag.1999.063.2.13DOI: 10.1180/minmag.1999.063.2.13
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tetraferriannite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tetraferriannite-7333},
  note      = {Accessed 2026-05-11}
}