Enargite

Cu3AsS4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Eng
Discovered
1850
Also known as
  • Clarit
  • Clarita
  • Clarite (of Sandberger)
  • +6 more

History

A mineral that breaks cleanly along flat planes is easy to recognise, and that quality gave enargite its name. The word comes from the Greek enarges — meaning distinct — chosen for the sharp, distinct cleavage along which its crystals split.

The mineral was first described in 1850, by the German mineralogists Johann Friedrich August Breithaupt and Carl Friedrich Plattner. They examined material from the copper mines of the San Francisco vein, in the Junín Department of Peru — still recognised as the type locality, the place where the species was first defined.

From there enargite turned up in copper districts across the Americas and beyond. Notable specimens came from Butte, Montana; the San Juan Mountains of Colorado; and the Tintic and Bingham Canyon districts of Utah. Mexico, Argentina, Chile, the Peruvian camps of Morococha and Cerro de Pasco, and the island of Luzon in the Philippines all yielded the mineral as well. In several of these places it gathered in quantities large enough to be worked as a copper ore — the role that earned it a place in mining history.

Industrial & practical applications

Where it gathers in quantity, enargite is mined as an ore of copper — nearly half its weight is the metal. It concentrates in one kind of deposit above all: high-sulfidation epithermal systems. These are ore bodies formed near the surface by hot, strongly acidic fluids rising from a magma below. They often sit close to a porphyry copper deposit — the large, low-grade bodies that supply most of the world's copper. Butte in Montana, Chuquicamata in Chile, and the copper camps of Peru and the Philippines have all produced it.

The catch is the arsenic. Enargite carries a heavy load of it — the chemical formula is Cu₃AsS₄ — and arsenic is treated by smelters as a troublesome impurity, not a product. Melted with the copper, it is diluted and emitted in the gas and slag streams, which forces special collection and handling so it does not escape as toxic dust or fume. Buyers cap how much arsenic a concentrate may carry and charge a penalty above that limit, which makes enargite-rich ore costly to sell.
The usual fix is roasting — heating the concentrate so the arsenic volatilises and leaves through the gas before smelting. Even so, the captured arsenic becomes a toxic waste that must be locked into a stable, disposable form.

Beyond the copper it carries, enargite is also collected as mineral specimens — its sharp, lustrous black crystals are prized. Because the mineral is an arsenic compound, specimens are handled with care: dust should not be inhaled, and hands are washed after contact.

Where it forms, where it's found

Geological setting

A mineral of moderate temperature vein and replacement deposits.

Type locality
San Francisco vein
  1. Morococha District
  2. Yauli Province
  3. Junín
  4. Peru
1,005recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Greyish-black to black · grey/rose-brown in reflected light.
Streak
Black.
Tenacity
brittle
Cleavage
Perfect

Perfect on (110), imperfect on (100) and (010), indistinct (001).

Fracture
Irregular/Uneven
Density
4.4 g/cm³

Optical

Pleochroism
Weak
Optical colour
Grey to light pink brown
Anisotropism
Strong dark violet red or olive green
Internal reflections
Deep red
Tropism
Anisotropic
Reflectance R%
(24.8,26.2) 400, (26.6,26.0) 420, (26.5,25.6) 440, (26.5,25.9) 460, (26.2,25.8) 480, (25.6,25.6) 500, (24.9,25.3) 520, (24.4,25.2) 540, (24.0,25.2) 560, (23.8,25.4) 580, (23.8,25.9) 600, (24.1,26.5) 620, (24.6,26.9) 640, (25.2,26.9) 660, (25.6,26.8) 680, (25.7,26.7) 700
Reflected-light panel
25.1 %anisotropic · dual curve
Specimen sRGB 179, 125, 72
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong dark violet red or olive green
Reflected colour
Grey to light pink brown
Internal reflections
Deep red

Crystallography

Crystal system
Orthorhombic
Space group
#34
Cell parameters
a = 7.4127(16) Å · b = 6.4404(15) Å · c = 6.1577(14) Å
Ratio a:b:c
1 : 0.869 : 0.831
Z
2
Morphology

Crystals tabular on (001), or prismatic. May be striated parallel to "c." Also found as massive material, may be granular.

Twinning

Common on (230), sometimes as star-shaped cyclic trillings. Note that the twin law is erroneously given as (320) in the literature; an explanation the error, which was recognised by Pete Richards, is given in the FMF link (mineral-forum.com) in the references section.

Comment

Cell parameters from Karanović et al. (2002).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper363.546190.638
48.41%
16SSulfurSulfur432.060128.240
32.56%
33AsArsenicArsenic174.92274.922
19.03%
Total393.800100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Sb
  • Fe
  • Pb
  • Zn
  • Ag
  • Ge

Synonyms

  • Clarit
  • Clarita
  • Clarite (of Sandberger)
  • Garbyit
  • Garbyita
  • Garbyite
  • Guayacanit
  • Guayacanita
  • Guayacanite

In other languages

French
Cu3AsS4 · énargite
German
Clarit · Enargit · Garbyit · Guayacanit
Spanish
enargita
Italian
Enargite
Portuguese
enargita · Enargite
Japanese
硫砒銅鉱
Chinese
硫砷銅礦 · 硫砷铜矿
Simplified Chinese
硫砷铜矿
Russian
энаргит
Arabic
إينارغيت

Classification

Strunz
10th ed.

2.KA.05

  • 2Sulfides and SulfosaltsClass
  • 2.KSulfarsenates, SulfantimonatesDivision
  • 2.KASulfarsenates with (As,Sb)S4 tetrahedraGroup
  • 2.KA.05EnargiteSpecies
Dana
8th ed.

03.02.01.01

  • 03SulfosaltsClass
  • 03.02ø = 4Type
  • 03.02.01— unnamed intermediate level —Group
  • 03.02.01.01EnargiteSpecies
CIM

6.3.1

  • 6Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and SulphohalidesClass
  • 6.3Sulpharsenates and sulphantimonatesGroup
  • 6.3.1EnargiteSpecies

Group, growth & confusion

Often grow together
13 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Mémoires du Bureau de Recherches Géologiques et Minières: 54: 99-124.
  2. 1850Breithaupt, J.F.A.; Plattner, C.F. (1850) Enargit, ein neues Mineral aus der Ordnung der Glanze. Annalen der Physik, 156 (7). 383-391 doi:10.1002/andp.18501560708DOI: 10.1002/andp.18501560708
  3. 1859Field, F. (1859) Description of a new mineral species from Chili. American Journal of Science, 27, 52. (as guayacanite)
  4. 1874Sandberger, F. (1874) Correspondance, Communications to Professor G. Leonhard. Neues Jahrbuch für Mineralogie, Geognosie, Geologie und Petrefaktenkunde, 1874, 960-960. (as clarite)
  5. 1875Sandberger, F. (1875) Über den Clarit. Neues Jahrbuch für Mineralogie, Geognosie, Geologie und Petrefaktenkunde, 1875, 382-388.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Enargite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/enargite-1380},
  note      = {Accessed 2026-05-11}
}