Guanajuatite

Bi2Se3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gj
Discovered
1873
Also known as
  • Castillite (of Domeyko)
  • Frenzelit
  • Frenzelita
  • +4 more

Where it forms, where it's found

Geological setting

Low to moderate temperature hydrothermal deposits.

Type locality
Santa Catarina Mine
  1. Rancho Calvillo
  2. Santa Rosa
  3. Sierra de Santa Rosa
  4. Guanajuato Municipality
  5. Guanajuato
  6. Mexico
36recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Bluish gray
Streak
Shiny gray
Tenacity
sectile
Cleavage
Distinct/Good

Distinct (010) indistinct (001)

Density
6.25 g/cm³

Optical

Pleochroism
Visible
Optical colour
White with yellowish hue
Anisotropism
Strong
Tropism
Anisotropic
Reflectance R%
(41.2,51.8) 400, (41.8,51.8) 420, (42.3,51.9) 440, (42.8,51.9) 460, (43.3,52.0) 480, (43.3,52.0) 500, (43.3,52.0) 520, (43.1,52.0) 540, (42.9,52.0) 560, (42.7,52.2) 580, (42.4,52.2) 600, (42.2,52.1) 620, (41.9,51.9) 640, (41.5,51.6) 660, (41.2,51.2) 680, (40.8,50.7) 700
Reflected-light panel
42.3 %anisotropic · dual curve
Specimen sRGB 230, 163, 90
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong
Reflected colour
White with yellowish hue

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 11.37 Å · b = 11.55 Å · c = 4.054 Å
Ratio a:b:c
1 : 1.016 : 0.357
Z
4
Morphology

Acicular crystals, massive (granular, foliated, fibrous)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth2208.980417.960
63.82%
34SeSeleniumSelenium378.971236.913
36.18%
Total654.873100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • S

Synonyms

  • Castillite (of Domeyko)
  • Frenzelit
  • Frenzelita
  • Frenzelite
  • Guanajuatiet
  • Selenobismutite (of Vernadsky)
  • Selenwismutglanz

In other languages

French
Guanajuatite
German
Guanajuatit
Spanish
Guanajuatita
Italian
Guanajuatite
Chinese
硒铋矿
Simplified Chinese
硒铋矿
Traditional Chinese
硒鉍礦

Classification

Strunz
10th ed.

2.DB.05

  • 2Sulfides and SulfosaltsClass
  • 2.DMetal Sulfides, M: S = 3 :4 and 2:3Division
  • 2.DBM:S = 2:3Group
  • 2.DB.05GuanajuatiteSpecies
Dana
8th ed.

02.11.02.04

  • 02SulfidesClass
  • 02.11AmBnXp, with (m+n):p = 2:3Type
  • 02.11.02Stibnite Group (Orthorhombic: Pbnm)Group
  • 02.11.02.04GuanajuatiteSpecies
CIM

3.7.19

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.7Sulphides etc. of V, As, Sb and BiGroup
  • 3.7.19GuanajuatiteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
9 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1858Hermann, R. (1858) Untersuchungen einiger Wismutherze, sowie über Oxysulphuret von Wismuth. Journal für Praktische Chemie: 75: 448-453.
  2. 1873Fernandez, V. (1873) La guanajuatita. La República: 6(40): 3-4.
  3. 1873Fernandez, V. (1873) La guanajuatita. La República: 6(42): 2-3.
  4. 1873Castillo, D.A. (1873) Descubrimiento de una nueva especie mineral de bismuto. La Naturaleza: 2: 274-276.
  5. 1874Frenzel, A. (1874) Mineralogisches 5. Selenwismuthglans. Neues Jahrbuch für Mineralogie, Geologie und Palaontologie: 1874: 679-681.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Guanajuatite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/guanajuatite-1761},
  note      = {Accessed 2026-05-11}
}