Guimarãesite

Ca2Be4Zn5(PO4)6(OH)4 · 6H2O
IMA status
  • Approved
IMA symbol
Grã
IMA approved
2006
Also known as
  • Guimarãesiet
  • IMA2006-028

Where it forms, where it's found

Geological setting

late fracture-filling mineral in a phosphate-rich granite pegmatite

Type locality
Guimarãesite occurrence
  1. Piauí valley
  2. Taquaral
  3. Itinga
  4. Minas Gerais
  5. Brazil

-16.7222°, -41.8930°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
brown
Streak
White
Tenacity
brittle
Cleavage
Perfect

perfect cleavage on (100) and good cleavage on (010) (by analogy)

Fracture
Irregular/Uneven
Density
2.963 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 55 – 75° · 2V calc = 70°
Refractive index
1.596 – 1.602
Surface relief
Moderate
Principal indices
nα 1.596 · nβ 1.600 · nγ 1.602
Pleochroism
Non-pleochroic
UV response
none
Michel-Lévy diagramhighlighted lineδ = 0.0060
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]60 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation60 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 15.98(1) Å · b = 11.84(2) Å · c = 6.63(1) Å
Cell angles
β = 95.15(15) °
Ratio a:b:c
1 : 0.741 : 0.415
Z
2
Type-locality form

peripheral zones (up to 0.1 mm thick) in crystals of roscherite-group minerals.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3415.999543.966
45.75%
30ZnZincZinc565.380326.900
27.49%
15PPhosphorusPhosphorus630.974185.844
15.63%
20CaCalciumCalcium240.07880.156
6.74%
4BeBerylliumBeryllium49.01236.048
3.03%
1HHydrogenHydrogen161.00816.128
1.36%
Total1189.042100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Guimarãesiet
  • IMA2006-028

In other languages

German
Guimarãesit · IMA 2006-028
Italian
guimarãesite

Classification

Strunz
10th ed.

8.DA.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DAWith small (and occasionally larger) cationsGroup
  • 8.DA.10GuimarãesiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2007Chukanov, Nikita V., Atencio, Daniel, Zadov, Alexander E., Filho, Luis A.D. Menezes, Coutinho, Jose M.V. (2007) Guimarãesite, a New Zn-dominant Monoclinic Roscherite-group Mineral from Itinga, Minas Gerais, Brazil. New Data on Minerals, 42. 11-15
  2. 2022(2022) Guimarãesite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Guimarãesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/guimaraesite-30764},
  note      = {Accessed 2026-05-11}
}