Hydroxylpyromorphite

Pb5(PO4)3(OH)
IMA status
  • Approved
IMA symbol
Hpm
IMA approved
2017
Also known as
  • Hydroxylpyromorphiet
  • Hydroxypyromorphite
  • IMA2017-075
  • +1 more

Where it forms, where it's found

Geological setting

In a formation comprised primarily of metagraywacke and conglomeratic, ferruginous quartzite.

Type locality
Copps Mine
  1. Marenisco
  2. Gogebic iron range
  3. Gogebic County
  4. Michigan
  5. USA

46.4568°, -89.6608°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

indistinct cleavage was observed on (001)

Fracture
Irregular/Uneven
Density
7.32 g/cm³

Optical

Optical type
Uniaxial (-)
UV response
None
Notes

The predicted average index of refraction based upon the Gladstone-Dale relationship is 2.04

Crystallography

Crystal system
Hexagonal
Space group
P63/m 2/c 2/m
Cell parameters
a = 9.787(1) Å · c = 7.307(1) Å
Z
2
Morphology

Elongated prismatic, showing the (100) prism terminated by the (101) pyramid.

Type-locality form

Occurs as aggregates of randomly oriented hexagonal prisms, primarily between about 20–35 μm in length and 6–10 μm in diameter.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead5207.2001036.000
77.43%
8OOxygenOxygen1315.999207.987
15.55%
15PPhosphorusPhosphorus330.97492.922
6.94%
1HHydrogenHydrogen11.0081.008
0.08%
Total1337.917100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hydroxylpyromorphiet
  • Hydroxypyromorphite
  • IMA2017-075
  • Unnamed (OH-analogue of Pyromorphite)

In other languages

German
Hydroxylpyromorphit · IMA 2017-075

Classification

Strunz
10th ed.

8.BN.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BNWith only large cations, (OH, etc.):RO4 = 0.33:1Group
  • 8.BN.05HydroxylpyromorphiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1938Klement, Robert (1938) Basische Phosphate zweiwertiger Metalle II. Blei‐Hydroxylapatit. Zeitschrift für anorganische und allgemeine Chemie, 237 (2). 161-171 doi:10.1002/zaac.19382370206DOI: 10.1002/zaac.19382370206
  2. 1970Engel, G. (1970) Hydrothermalsynthese von Bleihydroxylapatiten Pb5(XO4)3OH mit X = P, As, V. Die Naturwissenschaften, 57 (7) 355 doi:10.1007/bf01173112DOI: 10.1007/bf01173112
  3. 1995Brückner, S., Lusvardi, G., Menabue, L., Saladini, M. (1995) Crystal structure of lead hydroxyapatite from powder X-ray diffraction data. Inorganica Chimica Acta, 236 (1). 209-212 doi:10.1016/0020-1693(95)04636-nDOI: 10.1016/0020-1693(95)04636-n
  4. 1998Barinova, A.V., Bonin, M., Pushcharovskii, D.Y., Rastsvetaeva, R.K., Schenk, K., Dimitrova, O.V. (1998): Crystal structure of synthetic hydroxylpyromorphite Pb5(PO4)3(OH). Crystallography Reports, 43, 189-192.
  5. 2007Kirchner, E. Ch., Mrazek, R. and Wimmer, H. (2007): Neue Mineralfunde von Bergbauhalden Radhausberg Süd (Weißental) Kreuzkogl. Miner. Archiv Salzburg, 12, 251-254. (in German)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydroxylpyromorphite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydroxylpyromorphite-31566},
  note      = {Accessed 2026-05-11}
}