Hydroxylapatite

Ca5(PO4)3OH
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hap
Discovered
1856
Also known as
  • Apatite-(CaOH)
  • Fluor-hydroxylapatite
  • Hidroxilapatito
  • +3 more

Where it forms, where it's found

Geological setting

Originally found in fracture fillings in an argillaceous schist (St. Girons, France).

Abundant in sedimentary phosphate beds. Occasionally found in Talc-schist; in diallage-serpentine rock. May be be found in late-stage phosphate mineralization in granite pegmatites,

447recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent · Opaque
Colour
White · grey · yellow · green · violet · purple · red or brown

Ideally white; other colors usually due to staining

Streak
White
Tenacity
brittle
Cleavage
Poor/Indistinct

Poor on {0001) and on (1010)

Fracture
Conchoidal · Sub-Conchoidal · Fibrous
Density
3.10 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.644 – 1.651
Surface relief
Moderate
Principal indices
nω 1.651 · nε 1.644
Birefringence
0.007
Pleochroism
Non-pleochroic
Extinction
Parallel
UV response
Not usually fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P63/m
Cell parameters
a = 9.41 Å · c = 6.88 Å
Z
2
Morphology

Crystals short to long hexagonal prisms [0001], with (1010) and (1011) dominant; also thick tabular (0001), frequently in the crystals of hydrothermal origin in pegmatites and veins, with (1010), relatively large (0001), and often also (1011) or low pyramids. Very sharp crystals are uncommon and terminations are frequently rounded. Massive, coarse granular to compact.

Twinning

Rare contact twins on (1121). Twin plane <m>(1013) rare. Also twinning reported on (1010) and (1123).

Type-locality form

Concretions resembling chalcedony.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
41.41%
20CaCalciumCalcium540.078200.390
39.89%
15PPhosphorusPhosphorus330.97492.922
18.50%
1HHydrogenHydrogen11.0081.008
0.20%
Total502.307100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Apatite-(CaOH)
  • Fluor-hydroxylapatite
  • Hidroxilapatito
  • Hydro-apatite
  • Hydroxyapatit
  • Monite

In other languages

French
Hydroxy-apatite · Hydroxyapatite
German
Apatit-(CaOH) · Hydroxyapatit · Hydroxylapatit · Nanohydroxylapatit
Spanish
Apatito-(CaOH) · Hidroxiapatita · Hidroxiapatito · Hidroxilapatito
Italian
Hydroxylapatite · idrossilapatite
Portuguese
Cristais de hidroxiapatita · Hidroxiapatita · hidroxiapatite · Hidroxilapatite
Japanese
水酸燐灰石
Chinese
羟基磷灰石 · 羥磷灰石
Simplified Chinese
羟磷灰石
Traditional Chinese
羥磷灰石
Russian
Гидроксиапатит
Arabic
هيدروكسيل أباتيت

Classification

Strunz
10th ed.

8.BN.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BNWith only large cations, (OH, etc.):RO4 = 0.33:1Group
  • 8.BN.05HydroxylapatiteSpecies
Dana
8th ed.

41.08.01.03

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.08A5(XO4)3ZqType
  • 41.08.01Apatite GroupGroup
  • 41.08.01.03HydroxylapatiteSpecies
CIM

19.4.2

  • 19PhosphatesClass
  • 19.4Phosphates of CaGroup
  • 19.4.2HydroxylapatiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1856Shepard, C.U. (1856) Five new mineral species. American Journal of Science: s2(21-22): 96-99. (as Pyroclasite)
  2. 1882Shepard, C.U. (1882) On two new minerals, monetite and monite, with a notice of pyroclasite. American Journal of Science: 23(137): 400-405. (as Monite)
  3. 1912Schaller (1912) USGS Bull. 509: 89 (as Hydroxyapatite).
  4. 1919Bianchi (1919) Atti soc. ital. soc. Nat.: 458: 306.
  5. 1935Burri, Jakob, Parker, and Strunz (1935) Schweizerische mineralogische und petrographische Mitteilungen, Frauenfeld: 15: 327 (as Hydroxylapatit).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydroxylapatite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydroxylapatite-1992},
  note      = {Accessed 2026-05-11}
}