Pliniusite

Ca5(VO4)3F
IMA status
  • Approved
IMA symbol
Pli
IMA approved
2018
Also known as
  • IMA2018-031
  • Pliniusiet
  • Unnamed (V-dominant analogue of Fluorapatite)

Where it forms, where it's found

Geological setting

Fumaroles and a pyrometamorphic rock.

Pyrometamorphic rock. Fumaroles.

Type locality
Southern fumarole field
  1. Mountain 1004
  2. Tolbachik Volcanic field
  3. Milkovsky District
  4. Kamchatka Krai
  5. Russia

55.6686°, 160.2367°

6recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent · Translucent
Colour
Colorless or white
Streak
White
Density
3.402 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.738 – 1.763
Surface relief
High
Principal indices
nω 1.763 · nε 1.738
Michel-Lévy diagramhighlighted lineδ = 0.0250
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]250 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation250 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#108
Cell parameters
a = 9.5777(7) Å · c = 6.9659(5) Å
Z
2
Morphology

Hexagonal prismatic crystals.

Type-locality form

Hexagonal prismatic crystals up to 0.3 × 0.1 mm and open-work aggregates up to 2 mm across.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium540.078200.390
35.52%
8OOxygenOxygen1215.999191.988
34.03%
23VVanadiumVanadium350.942152.826
27.08%
9FFluorineFluorine118.99818.998
3.37%
Total564.202100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2018-031
  • Pliniusiet
  • Unnamed (V-dominant analogue of Fluorapatite)

In other languages

German
IMA 2018-031 · Pliniusit

Classification

Strunz
10th ed.

8.BN.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BNWith only large cations, (OH, etc.):RO4 = 0.33:1Group
  • 8.BN.05PliniusiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. Dong, Z. L.; Wei, B.; White, T. J. (2001): Study of calcium/lead apatite structure type for stabilising heavy metals. Materials Research Society Symposium Proceedings 658 (Solid-State Chemistry of Inorganic Materials III), GG6.33.1-GG6.33.6.
  2. 2011He, Qiang; Liu, Xi; Hu, Xiaomin; Li, Sicheng; Wang, Hejing (2011) Solid solution between lead fluorapatite and lead fluorvanadate apatite: Mixing behavior, Raman feature and thermal expansivity. Physics and Chemistry of Minerals, 38 (10). 741-752 doi:10.1007/s00269-011-0447-yDOI: 10.1007/s00269-011-0447-y
  3. 2018Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter No. 44, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (4) 1015-1021 doi:10.1180/mgm.2018.148DOI: 10.1180/mgm.2018.148
  4. 2020Koshlyakova, N.N., Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchkova, A.G., Kartashov, P.M., Sidorov, E.G., Pushcharovsky, D.Yu. (2020): A new solid solution with the garnet structure: the berzeliite–schaferite isomorphous series from Fumarole exhalations of the Tolbachik volcano, Kamchatka. Zapiski RMO (Proceedings of the Russian Mineralogical Society): 149(1): 69-84.
  5. 2022(2022) Pliniusite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pliniusite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pliniusite-53051},
  note      = {Accessed 2026-05-11}
}