Pieczkaite

Mn5(PO4)3Cl
IMA status
  • Approved
IMA symbol
Pzk
IMA approved
2014
Also known as
  • IMA2014-005
  • Pieczkaiet

Where it forms, where it's found

Geological setting

Granite pegmatite.

Type locality
Pegmatite No. 22 (Gottcha Claim)
  1. North Group
  2. Cross Lake
  3. Manitoba
  4. Canada

54.6833°, -97.8167°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Grey
Streak
Grayish-white
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.783 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.69 – 1.698
Surface relief
High
Principal indices
nω 1.694 – 1.698 · nε 1.690 – 1.694
UV response
Does not fluoresce under ultraviolet light
Michel-Lévy diagramhighlighted lineδ = 0.0040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]40 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
P63/m
Cell parameters
a = 9.504(4) Å · c = 6.347(3) Å
Unit cell volume
496.5 ų
Z
2
Morphology

Narrow veins to ~25 μm in apatite.

Parting
None observed
Type-locality form

As small patches and narrow veins in large crystals of apatite and (Mn,Cl)-bearing apatite in phosphate pods in the quartz core of a granitic pegmatite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese554.938274.690
46.16%
8OOxygenOxygen1215.999191.988
32.26%
15PPhosphorusPhosphorus330.97492.922
15.62%
17ClChlorineChlorine135.45035.450
5.96%
Total595.050100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2014-005
  • Pieczkaiet

In other languages

German
IMA 2014-005 · Pieczkait
Italian
pieczkaite

Classification

Strunz
10th ed.

8.BN.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BNWith only large cations, (OH, etc.):RO4 = 0.33:1Group
  • 8.BN.05PieczkaiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1975Engel, G.; Pretzsch, J.; Gramlich, V.; Baur, W. H. (1975) The crystal structure of hydrothermally grown manganese chlorapatite, Mn5(PO4)3Cl0.9(OH)0.1. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 31 (7). 1854-1860 doi:10.1107/s056774087500636xDOI: 10.1107/s056774087500636x
  2. 2014Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 20. Mineralogical Magazine, 78 (3) 549-558 doi:10.1180/minmag.2014.078.3.05DOI: 10.1180/minmag.2014.078.3.05
  3. 2015Tait, Kimberly, Ball, Neil A., Hawthorne, Frank C. (2015) Pieczkaite, ideally Mn5(PO4)3Cl, a new apatite-supergroup mineral from Cross Lake, Manitoba, Canada: Description and crystal structure. American Mineralogist, 100 (5) 1047-1052 doi:10.2138/am-2015-5117 DOI: 10.2138/am-2015-5117
  4. 2017(2017) Pieczkaite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2020Pieczka, Adam, Gołębiowska, Bożena, Jeleń, Piotr, Sitarz, Maciej, Szuszkiewicz, Adam (2020) Raman spectroscopic studies of O–H stretching vibration in Mn-rich apatites: A structural approach. American Mineralogist, 105 (9) 1385-1391 doi:10.2138/am-2020-7324DOI: 10.2138/am-2020-7324
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pieczkaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pieczkaite-46099},
  note      = {Accessed 2026-05-11}
}