Annabergite

Ni3(AsO4)2 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Anb
Discovered
1852
Also known as
  • Annabergitt
  • Arsenate of Nickel
  • Cordillerite
  • +9 more

History

Miners working the silver and cobalt veins of Saxony knew the apple-green crust long before anyone gave it a proper name. They called it a bloom — a soft, earthy coating that spread over weathered ore.

Axel Fredrik Cronstedt put it in print first. In 1758 he mistook the green stuff for a nickel oxide and gave it the Latin name Ochra niccoli — nickel ochre. Twenty years later, in 1778, Wallerius renamed it nickel bloom.

The modern name arrived in 1852. Henry James Brooke and William Hallowes Miller described the mineral properly and named it after Annaberg, the silver-mining town in Saxony where some of the first specimens were collected.

The green colour was more than a curiosity to those miners. A bright stain on the rock face told them that nickel and arsenic ores lay nearby, hidden in the unweathered vein below. The mineral was a sign to follow, not a thing to dig out.

Industrial & practical applications

Annabergite is not an ore and is not mined for industry. It forms only as a thin secondary crust where nickel-arsenic minerals have weathered, so it never gathers in the quantity a metal works would need.

What demand exists comes from collectors. Well-formed crystals are rare; the mineral usually appears as soft earthy masses and encrustations, and a clean apple-green specimen is prized for its colour.

A specimen is also a piece of arsenic chemistry. The mineral is a nickel arsenate, Ni₃(AsO₄)₂·8H₂O, which means the toxic element arsenic is locked into its structure.

Where it forms, where it's found

Geological setting

Oxide zone in a nickel-bearing sulfide deposit

An uncommon oxidation zone mineral in Ni-Co-As deposits, frequently post-mine on ores exposed to the atmosphere.

Type locality
Teichgräber Flacher vein
  1. Teichgräber deep adit
  2. Kippenhain Mine (Kippenhayn Mine)
  3. Schreckenberg
  4. Frohnau
  5. Annaberg-Buchholz
  6. Erzgebirgskreis
  7. Saxony
  8. Germany
453recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789101.5 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Weakly adamantine · vitreous · earthy when powdery.
Transparency
Transparent · Translucent
Colour
Green · light grey to light apple green · white · pale rose red when rich in cobalt.

Color may be light pink or light rose at Co:Ni ~ 1:1 (50-50 rule), then becomes white or gray, pale green, and apple-green in the Annabergite end of the series.

Streak
Pale green to white (paler than the mineral color).
Tenacity
sectile
Cleavage
Perfect

Perfect on (010), indistinct on (100), (102).

Flexible in thin {010} laminae

Density
3.07 g/cm³

Optical

Optical type
Biaxial (+/-) · 2V measured = 84° · 2V calc = 82°
Refractive index
1.622 – 1.687
Surface relief
High
Principal indices
nα 1.622 · nβ 1.658 · nγ 1.687
Birefringence
0.065
Pleochroism
Non-pleochroic
Dispersion
relatively weak r > v
Extinction
X=b, Z^c=36°
Luminescence
None?
UV response
Not fluorescent.
Notes

Usually biaxial positive, may be biaxial negative

Michel-Lévy diagramhighlighted lineδ = 0.0650
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]650 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation650 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 10.179(2) Å · b = 13.309(3) Å · c = 4.725(1) Å
Cell angles
β = 105.00(1) °
Ratio a:b:c
1 : 1.307 : 0.464
Z
2
Morphology

Crystals usually rare and of poor quality, prismatic to acicular [001] and flattened (010). Crystals are deeply striated or furrowed [001], also striated on (010) parallel to {h)l} or {_h0l}. Commonly as fine crystalline coatings or earthy.

Translation gliding
T(010), t[001].
Type-locality form

Green bladed crystals and green coatings

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
42.80%
28NiNickelNickel358.693176.079
29.44%
33AsArsenicArsenic274.922149.844
25.06%
1HHydrogenHydrogen161.00816.128
2.70%
Total598.035100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Co
  • Mg
  • Ca
  • Zn
  • Fe

Synonyms

  • Annabergitt
  • Arsenate of Nickel
  • Cordillerite
  • Niccoli calciforme
  • Nickel Arseniaté
  • Nickel Bloom
  • Nickel Green
  • Nickel Ocher
  • Nickelblüte
  • Nickelblüthe
  • Nickelocker
  • Ochra niccoli

In other languages

French
Annabergite · Cabrérite · Dudgeonite · Fleur de nickel · Mine de Cobalt verte · Nickel arseniaté · Nickelocre · Nickeocre
German
Annabergit · Nickelblüte
Spanish
Annabergita
Italian
Annabergite
Portuguese
Annabergita · annabergite
Japanese
ニッケル華
Chinese
鎳華
Russian
Аннабергит

Classification

Strunz
10th ed.

8.CE.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.40AnnabergiteSpecies
Dana
8th ed.

40.03.06.04

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.06Vivianite GroupGroup
  • 40.03.06.04AnnabergiteSpecies
CIM

20.10.9

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.10Arsenates of Co and NiGroup
  • 20.10.9AnnabergiteSpecies

Group, growth & confusion

Often grow together
7 minerals

Literature, links & citation

Citations
  1. 1758Cronstedt, Axel Fredrik (1758) Försök till en Mineralogie eller Mineral Rikets Upställning. J. A. Carlbohm, Stockholm.
  2. 1852Brooke, Henry J., Phillips, William (1852) An Elementary Introduction to Mineralogy (6th ed.)
  3. 1872Brezina (1872) Mineralogische und petrographische Mitteilungen, Vienna: 19.
  4. 1884Mügge (1884) Jahrbuch für Mineralogie: I: 53.
  5. 1889Heddle, Matthew Forster (1889) On Dudgeonite, Hydroplumbite, Plumbonacrite. and Plattnerite. Mineralogical Magazine, 8 (39) 200-203 doi:10.1180/minmag.1889.008.39.07 DOI: 10.1180/minmag.1889.008.39.07
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Annabergite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/annabergite-240},
  note      = {Accessed 2026-05-11}
}