Liebenbergite

Ni2(SiO4)
IMA status
  • Approved
IMA symbol
Lbb
Discovered
1973
Also known as
  • IMA1972-033
  • Liebenbergiet
  • Ni olivine

Where it forms, where it's found

Geological setting

Trevorite-ore nickel deposit between quartzite and serpentinized ultramafite.

Type locality
Bon Accord Ni deposit
  1. Barberton
  2. Mbombela Local Municipality
  3. Ehlanzeni District Municipality
  4. Mpumalanga
  5. South Africa

-25.6731°, 31.1695°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 6.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Yellow-green to bright green
Cleavage
Imperfect/Fair

(010) weak to moderate (100) weak

Density
4.92 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 80° · 2V calc = 88°
Refractive index
1.82 – 1.888
Surface relief
Very high
Principal indices
nα 1.820 · nβ 1.854 · nγ 1.888
Pleochroism
Visible

X = colorless to pale green Y = colorless to pale green Z = greenish yellow

Dispersion
weak r > v
Notes

α = b, β = c, γ = a

Michel-Lévy diagramhighlighted lineδ = 0.0680
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]680 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation680 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 4.727(1) Å · b = 10.191(3) Å · c = 5.955(2) Å
Ratio a:b:c
1 : 2.156 : 1.260
Unit cell volume
286.8 ų
Z
4
Twinning

None observed in type material

Type-locality form

Original liebenbergite filled the interstices between trevorite grains and measured up to 1 mm. They are almost completely replaced by secondary nickel serpentine, leaving only small irregular grains, few exceeding 150 microns in diameter.

Comment

Space Group: Pbnm:

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
28NiNickelNickel258.693117.386
56.04%
8OOxygenOxygen415.99963.996
30.55%
14SiSiliconSilicon128.08528.085
13.41%
Total209.467100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg
  • Fe
  • Co

Synonyms

  • IMA1972-033
  • Liebenbergiet
  • Ni olivine

In other languages

French
Liebenbergite
German
Dinickelorthosilikat · IMA 1972-033 · Liebenbergit
Italian
Liebenbergite
Russian
Либенбергит

Classification

Strunz
10th ed.

9.AC.05

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.ACNesosilicates without additional anions; cations in octahedral [6] coordinationGroup
  • 9.AC.05LiebenbergiteSpecies
Dana
8th ed.

51.03.01.03

  • 51Nesosilicates Insular Sio4 Groups OnlyClass
  • 51.03Insular SiO4 Groups Only with all cations in octahedral [6] coordinationType
  • 51.03.01Olivine groupGroup
  • 51.03.01.03LiebenbergiteSpecies
CIM

14.26.1

  • 14Silicates not Containing AluminumClass
  • 14.26Silicates of NiGroup
  • 14.26.1LiebenbergiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1973de Waal, Sybrand A., Calk, and Lewis C. (1973) Nickel minerals from Barberton, South Africa: VI. Liebenbergite, a nickel olivine. American Mineralogist, 58 (7-8) 733-735
  2. 1981Bish, David L. (1981) Cation ordering in synthetic and natural Ni-Mg olivine. American Mineralogist, 66 (7-8) 770-776
  3. 2001(2001) Liebenbergite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2001Ikeda, Ko; Onikura, Kyoichi; Nakamura, Yoshinori; Vedanand, Swaroop (2001) Optical Spectra of Nickel‐Bearing Silicate Gels Prepared by the Geopolymer Technique, with Special Reference to the Low‐Temperature Formation of Liebenbergite (Ni2SiO4). Journal of the American Ceramic Society, 84 (8). 1717-1720 doi:10.1111/j.1151-2916.2001.tb00904.xDOI: 10.1111/j.1151-2916.2001.tb00904.x
  5. 2005VALLEPU, Ramesh, MIKUNI, Akira, KOMATSU, Ryuichi, IKEDA, Ko (2005) Synthesis of liebenbergite nano-crystallites from silicate precursor gels prepared by geopolymerization. Journal of Mineralogical and Petrological Sciences, 100 (4) 159-167 doi:10.2465/jmps.100.159 DOI: 10.2465/jmps.100.159
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Liebenbergite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/liebenbergite-2397},
  note      = {Accessed 2026-05-11}
}