Calcio-olivine

Ca2(SiO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Caol
Also known as
  • Calcioolivine
  • Gamma-Ca2SiO4
  • Lime-Olivine
  • +1 more

Where it forms, where it's found

Geological setting

In skarnated xenoliths from acid ignimbrites.

Type locality
Xenolith no. 3
  1. Lakargi Mountain
  2. Upper Chegem volcanic caldera (Verkhnechegemskaya caldera)
  3. Chegemsky District
  4. Kabardino-Balkaria
  5. Russia
7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Very light yellowish rose (caused by microinclusions of bernalite) · colorless in thin sections
Cleavage

Cleavage or jointing in two directions.

Density
2.986 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 69 – 81°
Refractive index
1.64 – 1.659
Surface relief
Moderate
Principal indices
nα 1.640 – 1.644 · nβ 1.651 – 1.655 · nγ 1.655 – 1.659
Pleochroism
Non-pleochroic

colorless in thin section

Notes

optical data presented are for material from Verkhnechegemsk caldera (Kabardino-Balkaria, Russian Federation) (Zadov et al., 2007). Older data for other occurrences show some different values for R.I.

Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 5.07389(7) Å · b = 11.21128(14) Å · c = 6.75340(9) Å
Ratio a:b:c
1 : 2.210 : 1.331
Unit cell volume
384.17 ų
Z
4
Type-locality form

Rounded grains to 2-3 mm in size.

Comment

Space group Pbnm. Cell parameters from Zadov et al. (2008).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium240.07880.156
46.54%
8OOxygenOxygen415.99963.996
37.15%
14SiSiliconSilicon128.08528.085
16.31%
Total172.237100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Calcioolivine
  • Gamma-Ca2SiO4
  • Lime-Olivine
  • Podnoginite

In other languages

German
Calcio-Olivin
Italian
calcio-olivine

Classification

Strunz
10th ed.

9.AD.10

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.ADNesosilicates without additional anions; cations in [6] and/or greater coordinationGroup
  • 9.AD.10Calcio-olivineSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1929Tilley, C. E. (1929) On larnite (calcium orthosilicate, a new mineral) and its associated minerals from the limestone contact-zone of Scawt Hill, Co. Antrim. Mineralogical Magazine and Journal of the Mineralogical Society, 22 (125) 77-86 doi:10.1180/minmag.1929.022.125.01 DOI: 10.1180/minmag.1929.022.125.01
  2. 1942O'Daniel, H., Tscheischwili, L. (1942) Zur Struktur von γ-Ca2SiO4 und Na2BeF4. Zeitschrift für Kristallographie, 104 (1). 124-141 doi:10.1524/zkri.1942.104.1.124DOI: 10.1524/zkri.1942.104.1.124
  3. 1962Smith, D. K. (1962) Crystallographic changes with the substitution of aluminum for iron in dicalcium ferrite. Acta Crystallographica, 15 (11) 1146-1152 doi:10.1107/s0365110x62003011DOI: 10.1107/s0365110x62003011
  4. 1964Cruickshank, D. W. J. (1964) Refinements of structures containing bonds between Si, P, S or Cl and O or N. X. β-Ca2SiO4. Acta Crystallographica, 17 (6). 685-686 doi:10.1107/s0365110x64001724DOI: 10.1107/s0365110x64001724
  5. 1966Bridge, Thomas E. (1966) Bredigite, larnite, and γ dicalcium silicates from Marble Canyon. American Mineralogist, 51 (11-12) 1766-1774
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calcio-olivine — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calcio-olivine-9574},
  note      = {Accessed 2026-05-11}
}