Merlinoite

K5Ca2(Si23Al9)O64 · 24H2O
IMA status
  • Approved
IMA symbol
Mrl
Discovered
1977
Also known as
  • Merlinoiet

Where it forms, where it's found

Geological setting

In cavities in kalsilite-melilite rock.

Type locality
Cupaello Quarry
  1. Santa Rufina
  2. Rieti
  3. Rieti Province
  4. Lazio
  5. Italy

42.4167°, 12.9333°

17recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless · white
Streak
White
Density
2.14 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 56° · 2V calc = 88°
Refractive index
1.499 – 1.501
Surface relief
Moderate
Principal indices
nα 1.499 · nβ 1.500 · nγ 1.501
Dispersion
r > v
Extinction
X = b; Y = c; Z = a.
Michel-Lévy diagramhighlighted lineδ = 0.0020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]20 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Immm
Cell parameters
a = 14.116(7) Å · b = 14.229(6) Å · c = 9.946(6) Å
Ratio a:b:c
1 : 1.008 : 0.705
Z
1
Morphology

Rectangular prisms formed by the (100) and (010) pinacoids, terminated by two orthorhombic prisms with different development. Radiating fibrous spheroidal aggregates.

Type-locality form

Spheroidal radial aggregates with a diameter less than 1 mm.

Comment

Pseudo-tetragonal.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen8815.9991407.912
53.72%
14SiSiliconSilicon2328.085645.955
24.65%
13AlAluminiumAluminium926.982242.838
9.26%
19KPotassiumPotassium539.098195.490
7.46%
20CaCalciumCalcium240.07880.156
3.06%
1HHydrogenHydrogen481.00848.384
1.85%
Total2620.735100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • Merlinoiet

In other languages

German
IMA 1976-046 · Merlinoit
Italian
IMA1976-046 · merlinoite

Classification

Strunz
10th ed.

9.GC.15

  • 9SilicatesClass
  • 9.GTektosilicates with zeolitic H2O; zeolite familyDivision
  • 9.GCChains of doubly-connected 4-membered ringsGroup
  • 9.GC.15MerlinoiteSpecies
Dana
8th ed.

77.01.03.11

  • 77Tectosilicates ZeolitesClass
  • 77.01Zeolite group - True zeolitesType
  • 77.01.03Gismondine and related speciesGroup
  • 77.01.03.11MerlinoiteSpecies
CIM

16.12.14

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.12Aluminosilicates of Sr, Ba and ZnGroup
  • 16.12.14MerlinoiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1977Passaglia, E., Pongiluppi, D., Rinaldi, R. (1977) Merlinoite, a new mineral of the zeolite group. Neues Jahrbuch für Mineralogie, Monatshefte, 355-364
  2. 1978Fleischer, Michael, Cabri, Louis J. (1978) New mineral names. American Mineralogist, 63 (5-6) 598-600
  3. 1979Galli, E., Gottardi, G., Pongiluppi, D. (1979) The crystal structure of the zeolite merlinoite. Neues Jahrbuch für Mineralogie - Monatshefte, 1979. 1-9
  4. 1981Khomyakov, A.P., Kurova, T.A., Muravitskaya, G.N. (1981) Merlinoite (K,Ba)2Al3Si5O16-5H2O, first occurrence in the USSR. Doklady Acad. Nauk SSSR: 256: 172-174. (in Russian)
  5. 1981(1981) Chem Abs: 94: 106675. (abstract for above)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Merlinoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/merlinoite-2651},
  note      = {Accessed 2026-05-11}
}